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Merck

32428

Supelco

Orysastrobin

PESTANAL®, analytical standard

Sinónimos:

(2E)-2-(Methoxyimino)-2-{2-[(3E,5E,6E)-5-(methoxyimino)-4,6-dimethyl-2,8-dioxa-3,7-diazanona-3,6-dien-1-yl]phenyl}-N-methylacetamide

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About This Item

Fórmula empírica (notación de Hill):
C18H25N5O5
Número de CAS:
Peso molecular:
391.42
Beilstein/REAXYS Number:
11330196
UNSPSC Code:
41116107
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CNC(=O)C(=N\OC)\c1ccccc1CO\N=C(C)\C(=N\OC)\C(C)=N\OC

InChI

1S/C18H25N5O5/c1-12(20-25-4)16(22-26-5)13(2)21-28-11-14-9-7-8-10-15(14)17(23-27-6)18(24)19-3/h7-10H,11H2,1-6H3,(H,19,24)/b20-12+,21-13+,22-16+,23-17+

InChI key

JHIPUJPTQJYEQK-ZLHHXESBSA-N

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General description

Orysastrobin is one of the analogs of strobilurin fungicide.

Application

Orysastrobin may be used as an analytical reference standard for the determination of the analyte in:
  • Rice samples by high performance liquid chromatography equipped with ultraviolet (HPLC-UV) detection and LC coupled to tandem mass spectrometry (MS/MS) with electrospray ionization (ESI) and selected reaction monitoring (SRM) detection.
  • Food samples by atmospheric-pressure solids-analysis probe (ASAP) as well as desorption electrospray ionization-mass spectrometry (DESI-MS) techniques.
  • Hot pepper (Capsicum annuum L.) samples by modified QuEChERS (quick, easy, cheap, effective, rugged, and safe) method, followed by analysis using LC-MS/MS with SRM detection.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Certificados de análisis (COA)

Lot/Batch Number

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Visite la Librería de documentos

Multiresidue method for the determination of 227 pesticides in hot pepper (Capsicum annuum L.) by liquid chromatography with tandem mass spectrometry.
Zhu YZ, et al.
Journal of Separation Science, 37(20), 2947-2954 (2014)
Quantitative analysis of fungicide azoxystrobin in agricultural samples with rapid, simple and reliable monoclonal immunoassay.
Watanabe E and Miyake S
Food Chemistry, 136(2), 695-702 (2013)
Toxicological overview of a novel strobilurin fungicide, orysastrobin
van Ravenzwaay, B., et al.
Journal of Pesticide Science, 32(3), 270-277 (2007)
An assessment of atmospheric-pressure solids-analysis probes for the detection of chemicals in food.
Fussell RJ, et al.
TrAC, Trends in Analytical Chemistry, 29(11), 1326-1335 (2010)
Simultaneous determination of orysastrobin and its isomers in rice using HPLC-UV and LC-MS/MS.
Kwon CH, et al.
Journal of Agricultural and Food Chemistry, 59(20), 10826-10830 (2011)

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