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Merck

930059

Sigma-Aldrich

S-Phenyl methanethioate

Sinónimos:

Phenyl thioCORMate, Phenyl thioformate

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About This Item

Fórmula empírica (notación de Hill):
C7H6OS
Número de CAS:
Peso molecular:
138.19
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.06

form

liquid

Quality Level

refractive index

n/D 1.586

density

1.134 g/mL

functional group

thioether

storage temp.

−20°C

SMILES string

[H]C(SC1=CC=CC=C1)=O

Application

S-phenyl methanethioate is an effective CO releasing molecule (CORM) developed by the lab of Sarah Tasker as part of a series of thioformate based CORMs called thioCORMates. p-NO2 phenyl thioformate generates CO over the course of several minutes to allow for on-demand generation of CO for variety of reactions.

This and the other thioCORMates are cost effective CORMs that when activated with simple amines, can be used to generate a near quantitative amount of CO safely without the usage of gas cylinders. These are compatible with a variety of carbonylation reactions, as well as existing COware glassware and components.

ThioCORMate: Tunable and Cost-Effective Carbon Monoxide-Releasing Molecule

Learn more about CO releasing molecules from Prof. Skrydstrup

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Precios

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Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

221.0 °F

flash_point_c

105 °C


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Contenido relacionado

The Tasker group's work focuses on the synthesis and utilization of stoichiometric CO-releasing molecules (CORMs) as alternatives to pressurized cylinders when the gas has safety, stability, or other practical handling concerns.

The Tasker group's work focuses on the synthesis and utilization of stoichiometric CO-releasing molecules (CORMs) as alternatives to pressurized cylinders when the gas has safety, stability, or other practical handling concerns.

The Tasker group's work focuses on the synthesis and utilization of stoichiometric CO-releasing molecules (CORMs) as alternatives to pressurized cylinders when the gas has safety, stability, or other practical handling concerns.

The Tasker group's work focuses on the synthesis and utilization of stoichiometric CO-releasing molecules (CORMs) as alternatives to pressurized cylinders when the gas has safety, stability, or other practical handling concerns.

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