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Merck

930105

Sigma-Aldrich

S-(4-nitrophenyl) methanethioate

≥95%

Sinónimos:

p-NO2-phenyl thioCORMate, p-NO2-phenyl thioformate

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About This Item

Fórmula empírica (notación de Hill):
C7H5NO3S
Número de CAS:
Peso molecular:
183.18
UNSPSC Code:
12352101
NACRES:
NA.06

Quality Level

assay

≥95%

form

powder

reaction suitability

reaction type: C-C Bond Formation

functional group

nitro
thioether

storage temp.

2-8°C

SMILES string

[H]C(SC1=CC=C([N+]([O-])=O)C=C1)=O

Application

S-(4-nitrophenyl) methanethioate is an effective CO releasing molecule (CORM) developed by the lab of Sarah Tasker as part of a series of thioformate based CORMs called thioCORMates. p-NO2 phenyl thioformate generates CO rapidly for faster reactions that require instantaneous on-demand generation of CO. using only a simple amine to activate it.

This and the other thioCORMates are cost effective CORMs that when activated with simple amines, can be used to generate a near quantitative amount of CO safely without the usage of gas cylinders. These are compatible with a variety of carbonylation reactions, as well as existing COware glassware and components.

ThioCORMate: Tunable and Cost-Effective Carbon Monoxide-Releasing Molecule

Learn more about CO releasing molecules from Prof. Skrydstrup

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Descripción
Precios

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Contenido relacionado

The Tasker group's work focuses on the synthesis and utilization of stoichiometric CO-releasing molecules (CORMs) as alternatives to pressurized cylinders when the gas has safety, stability, or other practical handling concerns.

The Tasker group's work focuses on the synthesis and utilization of stoichiometric CO-releasing molecules (CORMs) as alternatives to pressurized cylinders when the gas has safety, stability, or other practical handling concerns.

The Tasker group's work focuses on the synthesis and utilization of stoichiometric CO-releasing molecules (CORMs) as alternatives to pressurized cylinders when the gas has safety, stability, or other practical handling concerns.

The Tasker group's work focuses on the synthesis and utilization of stoichiometric CO-releasing molecules (CORMs) as alternatives to pressurized cylinders when the gas has safety, stability, or other practical handling concerns.

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