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908576

Sigma-Aldrich

WinterGreen photocage

≥95%

Sinónimos:

(1,3,5,5,7,9-Hexamethyl-dipyrrolo[1,3,2]diazaborinin-10-yl)methanol, 4,4′-Dimethyl-8-hydroxymethyl-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene, BODIPY photocage, Imidazole-protected BODIPY alcohol

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About This Item

Fórmula empírica (notación de Hill):
C16H23BN2O
Número de CAS:
2230509-59-6
Peso molecular:
270.18

assay

≥95%

form

powder or crystals

storage temp.

2-8°C

Application

Green-light absorbing photocage. Easily functionalized to ester with DCC/EDC couplings for photorelease of carboxylic acids.

Other Notes

Arthur Winter Professor Product Portal

In search of the perfect photocage: structure-reactivity relationships in meso-methyl BODIPY photoremovable protecting groups

BODIPY-Derived Photoremovable Protecting Groups Unmasked with Green Light

Legal Information

US Patent Application #16/140,218

related product

Referencia del producto
Descripción
Precios

908584

WinterRed photocage, ≥95%

908606

WinterGreen carbamoyl imidazole photocage, ≥95%

914339

Fmoc-L-Lys(Nvoc)-OH, ≥98%

914525

o-Nitropiperonyl-O-tyrosine

915793

Methyl-o-nitropiperonyllysine, ≥95%

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
MKCL1916

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Pratik P Goswami et al.
Journal of the American Chemical Society, 137(11), 3783-3786 (2015-03-10)
Photoremovable protecting groups derived from meso-substituted BODIPY dyes release acetic acid with green wavelengths >500 nm. Photorelease is demonstrated in cultured S2 cells. The photocaging structures were identified by our previously proposed strategy of computationally searching for carbocations with low-energy
Tomáš Slanina et al.
Journal of the American Chemical Society, 139(42), 15168-15175 (2017-10-19)
A detailed investigation of the photophysical parameters and photochemical reactivity of meso-methyl BODIPY photoremovable protecting groups was accomplished through systematic variation of the leaving group (LG) and core substituents as well as substitutions at boron. Efficiencies of the LG release

Contenido relacionado

Winter Group – Professor Product Portal

Research in the Winter lab focuses on the development of new chemical tools for biological and medical applications. Philosophically, we take the view that many problems in biology are at heart problems in mechanistic physical organic chemistry

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

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