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745480

Sigma-Aldrich

Zinc isopropylsulfinate

95%

Sinónimos:

Baran Isopropylation Reagent, Baran IPS Reagent, Bis((isopropylsulfinyl)oxy)zinc, IPS

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About This Item

Fórmula empírica (notación de Hill):
C6H14O4S2Zn
Número de CAS:
1416821-55-0
Peso molecular:
279.69
Número MDL:
MFCD24386390
Código UNSPSC:
12352001
ID de la sustancia en PubChem:
329764984
NACRES:
NA.22

Nivel de calidad

100

Ensayo

95%

Formulario

solid

idoneidad de la reacción

reaction type: Allylation
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
reagent type: diversification reagent

mp

161-166 °C

grupo funcional

sulfinic acid

cadena SMILES

CC(C)S(=O)O[Zn]OS(=O)C(C)C

InChI

1S/2C3H8O2S.Zn/c2*1-3(2)6(4)5;/h2*3H,1-2H3,(H,4,5);/q;;+2/p-2

Clave InChI

PEEMMWYYSHSBTQ-UHFFFAOYSA-L

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Categorías relacionadas

Aplicación

Zinc isopropylsulfinate (IPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Ligadura / enlace

Frequently Asked Questions are available for this Product.

Nota de preparación

may contain up to 1 mole eq ZnCl2

Otras notas

Previously sold under product number L511161

Palabra de señalización

Danger

Frases de peligro

H314,H335,H410

Clasificaciones de peligro

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

8A - Combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
MKCN1076
MKCJ2637
MKCD0333
MKCB0914V
MKBX5822V

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Si necesita una versión concreta, puede buscar un certificado específico por el número de lote.

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Visite la Librería de documentos

Meiqi Niu et al.
eLife, 9 (2020-07-03)
The intraparietal sulcus (IPS) is structurally and functionally heterogeneous. We performed a quantitative cyto-/myelo- and receptor architectonical analysis to provide a multimodal map of the macaque IPS. We identified 17 cortical areas, including novel areas PEipe, PEipi (external and internal
Bonnie Bailet et al.
The Science of the total environment, 745, 140948-140948 (2020-08-01)
Ecological assessment of lakes and rivers using benthic diatom assemblages currently requires considerable taxonomic expertise to identify species using light microscopy. This traditional approach is also time-consuming. Diatom metabarcoding is a promising alternative and there is increasing interest in using
Jasmine Siew Min Chia et al.
Frontiers in pharmacology, 11, 92-92 (2020-03-21)
Zerumbone has shown great potential in various pathophysiological models of diseases, particularly in neuropathic pain conditions. Further understanding the mechanisms of action is important to develop zerumbone as a potential anti-nociceptive agent. Numerous receptors and pathways function to inhibit and
Rie Poulsen et al.
Trials, 18(1), 579-579 (2017-12-05)
Common mental disorders are important contributors to the global burden of disease and cause negative effects on both the individual and society. Stress-related disorders influence the individual's workability and cause early retirement pensions in Denmark. There is no clear evidence
Christopher A Barwacz et al.
The International journal of oral & maxillofacial implants, 33(5), 1126-1135 (2018-09-20)
To evaluate the influence that three different implant-abutment interface designs had on peri-implant mucosal outcomes as assessed by the pink esthetic score (PES) 3 years after delayed implant placement and immediate provisionalization. Adult subjects (n = 141) requiring replacement of
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