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534102

Sigma-Aldrich

Methylamine solution

greener alternative

33 wt. % in absolute ethanol ((denatured with 1% toluene))

Sinónimos:

Monomethylamine

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About This Item

Fórmula lineal:
CH3NH2
Número de CAS:
74-89-5
Peso molecular:
31.06
Beilstein/REAXYS Number:
741851
MDL number:
MFCD00008104
UNSPSC Code:
12352302
PubChem Substance ID:
24878015
NACRES:
NA.22
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Quality Level

200

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

33 wt. % in absolute ethanol ((denatured with 1% toluene))

impurities

≤1.0% water

refractive index

n20/D 1.360-1.372

density

0.756 g/mL at 25 °C

functional group

amine

greener alternative category

, Enabling

storage temp.

2-8°C

SMILES string

CN

InChI

[1S/CH5N/c1-2/h2H2,1H3]
1S/CH5N/c1-2/h2H2,1H3

InChI key

[BAVYZALUXZFZLV-UHFFFAOYSA-N]
BAVYZALUXZFZLV-UHFFFAOYSA-N

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General description

Methylamine solution is a 33wt.% solution of methylamine in absolute ethanol. Methylamine is an aliphatic primary amine.[1] It participates in the synthesis of isothiazolium salts.[2] Chemical degradation of methylamine solution of γ-irradiated poly(ε-caprolactone) has been described.[3] Maillard reaction of D-glucose and methylamine in aqueous acetic acid has been reported.[4]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Methylamine solution in absolute ethanol can be used as a precursor that facilitates the synthesis of perovskite based materials. It can also be used as a deactivating agent to study the catalytic performance of acidic macroporous ion exchange resins. It can be annealed to reduce impurity in the grain boundaries, improve the stability and efficiency of the perovskite solar cells.[5][6][7]

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Danger

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

-9.0 °F - closed cup

flash_point_c

-22.8 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
SHBR8751
BCCG6848
SHBQ6473
SHBQ4002
BCCJ7918

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Sigma-Aldrich

339245

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Bianca-Maria Bresolin et al.
Nanomaterials (Basel, Switzerland), 10(1) (2020-01-16)
The development of visible-light active photocatalysts is a current challenge especially energy and environmental-related fields. Herein, methylammonium lead iodide perovskite (MAIPb) was chosen as the novel semiconductor material for its ability of absorbing visible-light. An easily reproducible and efficient method
Preparation of the MacMillan imidazolidinones.
Samulis L and Tomkinson NCO.
Tetrahedron, 67(23), 4263-4267 (2011)
Formation of aromatic compounds from carbohydrates. V. Reaction of d-glucose and methylamine in slightly acidic, aqueous solution.
Olsson KJELL, et al.
Acta Chemica Scandinavica. Series B, 31(6), 469-469 (1977)
Five-membered rings. II. Inter and intramolecular reactions of simple amines with N-substituted phthalimides. Methylamine as a reagent for removal of a phthaloyl group from nitrogen.
Wolfe S and Hasan SK.
Canadian Journal of Chemistry, 48(22), 3572-3579 (1970)
Nucleophilic Attack on Some Isothiazolium Salts.
Mckinnon DM and Hassan ME.
Canadian Journal of Chemistry, 51(18), 3081-3086 (1973)
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Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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