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277177

Sigma-Aldrich

Methanol-13C

99 atom % 13C

Sinónimos:

13C Labeled methanol, Methyl alcohol-13C, Methyl-13C alcohol

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About This Item

Fórmula lineal:
13CH3OH
Número de CAS:
14742-26-8
Peso molecular:
33.03
Beilstein/REAXYS Number:
1697016
MDL number:
MFCD00037595
UNSPSC Code:
12352200
PubChem Substance ID:
24856739
NACRES:
NA.12

isotopic purity

99 atom % 13C

Quality Level

200

assay

99% (CP)

form

liquid

technique(s)

NMR: suitable
bio NMR: suitable

refractive index

n20/D 1.329 (lit.)

bp

65.4 °C (lit.)

mp

-98 °C (lit.)

density

0.815 g/mL at 25 °C

format

neat

mass shift

M+1

SMILES string

[13CH3]O

InChI

1S/CH4O/c1-2/h2H,1H3/i1+1

InChI key

OKKJLVBELUTLKV-OUBTZVSYSA-N

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General description

13CH3OH is isotopically enriched form of methyl alcohol.

Application

Methyl-13C alcohol is an external reference for the assignment of polymer constitution using nuclear magnetic resonance spectroscopy. It is used to study the proton transfer processes, which offering possibilities for the quantitative mechanism studies of proton-related catalytic reactions. This isotope-enrich solvent is used to confirm the distribution and arrangement of metals from metal organic frame work (MOF) using host-guest interaction study. Also used as trideuteromethylation reagent for the synthesis of deuterated drugs.

Packaging

This product may be available from bulk stock and can be packaged on demand. For information on pricing, availability and packaging, please contact Stable Isotopes Customer Service.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

target_organs

Eyes,Central nervous system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

51.8 °F - closed cup

flash_point_c

11.00 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
MBBD7673
MBBD8508
MBBD5671
MBBD3411
MBBD3920

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Xue Lu Wang et al.
Nature communications, 7, 11918-11918 (2016-06-18)
Proton transfer (PT) processes in solid-liquid phases play central roles throughout chemistry, biology and materials science. Identification of PT routes deep into the realistic catalytic process is experimentally challenging, thus leaving a gap in our understanding. Here we demonstrate an
Sven Bodenstedt et al.
Nature communications, 12(1), 4041-4041 (2021-07-02)
Optically pumped magnetometers (OPMs) based on alkali-atom vapors are ultra-sensitive devices for dc and low-frequency ac magnetic measurements. Here, in combination with fast-field-cycling hardware and high-resolution spectroscopic detection, we demonstrate applicability of OPMs in quantifying nuclear magnetic relaxation phenomena. Relaxation
Monica I Espinosa et al.
Nature communications, 11(1), 5564-5564 (2020-11-06)
Utilising one-carbon substrates such as carbon dioxide, methane, and methanol is vital to address the current climate crisis. Methylotrophic metabolism enables growth and energy generation from methanol, providing an alternative to sugar fermentation. Saccharomyces cerevisiae is an important industrial microorganism

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