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234826

Sigma-Aldrich

Bis(cyclopentadienyl)titanium(IV) dichloride

97%

Sinónimos:

Cp2TiCl2, Dichlorobis(1,3-cyclopentadiene)titanium, Dichlorodicyclopentadienyltitanium, Dichlorotitanocene, Cp2TiCl2, Di(cyclopentadienyl)titanium(IV) dichloride, Titanocene dichloride

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About This Item

Fórmula empírica (notación de Hill):
C10H10Cl2Ti
Número de CAS:
1271-19-8
Peso molecular:
248.96
EC Number:
215-035-9
MDL number:
MFCD00003723
UNSPSC Code:
12161600
PubChem Substance ID:
24854058
NACRES:
NA.22

Quality Level

100

assay

97%

reaction suitability

core: titanium
reagent type: catalyst

mp

260-280 °C (dec.) (lit.)

density

1.6 g/mL at 25 °C (lit.)

SMILES string

Cl[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChI key

XKLWATAZDMHTSH-UHFFFAOYSA-L

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Categorías relacionadas

Application

One-pot synthesis of α-methylene-γ-butyrolactones from benzaldehydes and bromomethylacrylates.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
STBK7215
STBK4429
STBK1876
STBJ2898
STBH8972

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Katherine M Buettner et al.
Dalton transactions (Cambridge, England : 2003), 40(37), 9580-9588 (2011-08-19)
Since the discovery of the anticancer activity of titanocene dichloride (TDC), many derivatives have been developed and evaluated. MKT4, a soluble, water-stable formulation of TDC, was used for both Phase I and Phase II human clinical trials. This formulation is
Alberto García-Peñas et al.
Journal of inorganic biochemistry, 106(1), 100-110 (2011-11-25)
Titanocene dichloride [Ti(η(5)-C(5)H(5))(2)Cl(2)] (1), has been grafted onto dehydrated hydroxyapatite (HAP), Al(2)O(3) and two mesoporous silicas MSU-2 (Michigan State University Silica type 2) and HMS (Hexagonal Mesoporous Silica), to give the novel materials HAP/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S1) (1.01 wt.% Ti), Al(2)O(3)/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S2)
Li Ming Gao et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 12(7), 959-967 (2007-06-15)
Functionalization of cyclopentadienyl (Cp) ligands and incorporation of these into a Ti(IV) center require careful design and selection of the appropriate synthetic routes to obtain the desired product in reasonably good yields. As part of our research efforts in the
Francesco Caruso et al.
Mini reviews in medicinal chemistry, 4(1), 49-60 (2004-02-03)
Most anticancer titanium compounds act against tumors in the gastrointestinal tract. Activity towards breast, lung and skin (melanoma) cancers is shown by some as well. Among their appealing properties is that they do not show common side effects of widely
Mauro Ravera et al.
Journal of inorganic biochemistry, 99(12), 2264-2269 (2005-10-08)
Titanocene dichloride exhibits anti-proliferative activity in a wide spectrum of murine and human tumors. Although it is still unclear as to which species are active in biological media, they all readily deliver Ti(IV) to transferrin, the protein that transports iron
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