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213462

Sigma-Aldrich

Borohidruro de sodio

ReagentPlus®, 99%

Sinónimos:

Tetrahidruroborato de sodio

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About This Item

Fórmula lineal:
NaBH4
Número de CAS:
16940-66-2
Peso molecular:
37.83
EC Number:
241-004-4
MDL number:
MFCD00003518
UNSPSC Code:
26111700
PubChem Substance ID:
57647923
NACRES:
NA.22

Quality Level

300

product line

ReagentPlus®

assay

99%

form

powder

reaction suitability

reagent type: reductant

mp

>300 °C (dec.) (lit.)

SMILES string

[BH4-].[Na+]

InChI

1S/BH4.Na/h1H4;/q-1;+1

InChI key

YOQDYZUWIQVZSF-UHFFFAOYSA-N

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General description

Sodium borohydride, also known as sodium tetrahydridoborate, is a highly basic boron hydride that is commonly used as a reducing agent. It reacts very slowly with water and acts as a catalyst and stabilizer.

Application

Sodium borohydride can be used as a reducing agent for the:
  • Synthesis of cobalt (II, III) oxide (Co3O4) from cobalt chloride (CoCl2) via a co-reduction process.
  • Solvent-free reduction of aldehydes and ketones to alcohols in the presence of solid acid as an activator.
  • Reductive amination of carbonyl compounds to secondary amines in the presence of silica-gel-supported sulfuric acid as a catalyst.
  • Raney nickel-catalyzed reduction of aromatic nitro compounds to aromatic amines.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react 1

supp_hazards

EUH014

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Sodium borohydride versus ammonia borane, in hydrogen storage and direct fuel cell applications
Umit DB,et al.
Energy & Environmental Science, 2, 627-637 (2009)
Magnetic Co 3 O 4/reduced graphene oxide nanocomposite as a superior heterogeneous catalyst for one-pot oxidative esterification of aldehydes to methyl esters
Vineeta P,et al.
Royal Society of Chemistry Advances, 5, 88567-88573 (2015)
Kinetics of Ru-catalyzed sodium borohydride hydrolysis
JS Z,et al.
Journal of Power Sources, 164, 772-781 (2007)
Dinesh Bhalothia et al.
Nanomaterials (Basel, Switzerland), 9(7) (2019-07-25)
Herein, ternary metallic nanocatalysts (NCs) consisting of Au clusters decorated with a Pt shell and a Ni oxide core underneath (called NPA) on carbon nanotube (CNT) support were synthesized by combining adsorption, precipitation, and chemical reduction methods. By a retrospective
Lin, X.M. et al.
Chemistry of Materials, 11, 198-198 (1999)
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