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Merck

46192

Supelco

Paraoxon-methyl

PESTANAL®, analytical standard

Sinónimos:

O,O-Dimethyl O-(4-nitrophenyl) phosphate

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About This Item

Fórmula empírica (notación de Hill):
C8H10NO6P
Número de CAS:
Peso molecular:
247.14
Beilstein/REAXYS Number:
1884904
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
NMR: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.523

mp

0-4 °C

suitability

passes test for identity (NMR)

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

COP(=O)(OC)Oc1ccc(cc1)[N+]([O-])=O

InChI

1S/C8H10NO6P/c1-13-16(12,14-2)15-8-5-3-7(4-6-8)9(10)11/h3-6H,1-2H3

InChI key

BAFQDKPJKOLXFZ-UHFFFAOYSA-N

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General description

Paraoxon-methyl is an oxon derivative and a major metabolite of parathionbelonging to the class of organophosphate insecticides.

Application

Paraoxon-methyl may be used as an analytical reference standard for the quantification of the analyte in oil samples and environmental samples using different chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 1 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 1

target_organs

Nervous system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

212.0 °F - closed cup

flash_point_c

100 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

Lot/Batch Number

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Los clientes también vieron

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1 of 2

Determination of organophosphorus pesticide residues in Cilento (Campania, Italy) virgin olive oil by capillary gas chromatography
Rastrelli L, et al.
Food Chemistry, 79(3), 303-305 (2002)
Characterization of organophosphorus compounds and phenylurea herbicides by positive and negative ion thermospray liquid chromatography-mass spectrometry
Barcelo.D and Albaiges.J
Journal of Chromatography A, 474(1), 163-173 (1989)
Applications of thermospray liquid chromatography-mass spectrometry in photochemical studies of pesticides in water
Durand.G, et al.
Journal of Chromatography A, 554(1-2), 233-250 (1991)
J Allen Crow et al.
Toxicology and applied pharmacology, 258(1), 145-150 (2011-11-22)
Oxons are the bioactivated metabolites of organophosphorus insecticides formed via cytochrome P450 monooxygenase-catalyzed desulfuration of the parent compound. Oxons react covalently with the active site serine residue of serine hydrolases, thereby inactivating the enzyme. A number of serine hydrolases other
R Srinivas et al.
Comparative biochemistry and physiology. Toxicology & pharmacology : CBP, 137(3), 261-269 (2004-06-03)
Moth larvae (Helicoverpa armigera Hübner) collected from field crops were tested for resistance to cypermethrin, fenvalerate, endosulfan, monocrotophos and quinolphos. Larvae were treated with a dose of the pesticide that would kill 99% of the susceptible insects. The percent survival

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