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Merck

T72605

Sigma-Aldrich

Trimethylacetyl chloride

99%

Sinónimos:

Pivaloyl chloride, Trimethylacetyl chloride

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About This Item

Fórmula lineal:
(CH3)3CCOCl
Número de CAS:
Peso molecular:
120.58
Beilstein:
385668
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
NACRES:
NA.22
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densidad de vapor

>1 (vs air)

Nivel de calidad

presión de vapor

36 mmHg ( 20 °C)

Ensayo

99%

índice de refracción

n20/D 1.412 (lit.)

bp

105-106 °C (lit.)

densidad

0.979 g/mL at 25 °C (lit.)

cadena SMILES

CC(C)(C)C(Cl)=O

InChI

1S/C5H9ClO/c1-5(2,3)4(6)7/h1-3H3

Clave InChI

JVSFQJZRHXAUGT-UHFFFAOYSA-N

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Aplicación

Widely used N-acylating agent for amines,[1] Schiff bases,[2] and pyrrolidinones[3] as well as O-acylating agent for alcohols,[4] lactones,[5] and saccharides.[6]

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1B

Riesgos supl.

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

55.4 °F - closed cup

Punto de inflamabilidad (°C)

13 °C - closed cup

Equipo de protección personal

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

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Los clientes también vieron

Tetrahedron, 49, 599-599 (1993)
The Journal of Organic Chemistry, 59, 1703-1703 (1994)
D Becker et al.
Carbohydrate research, 248, 129-141 (1993-10-04)
A new method has been developed for preparation of partially pivaloylated saccharides in one step from readily available starting materials. These intermediates were used in the synthesis of disaccharides and a glucosteroid.
Journal of Carbohydrate Chemistry, 12, 841-841 (1993)
Angewandte Chemie (International Edition in English), 32, 72-72 (1993)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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