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Merck
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Key Documents

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A53605

Sigma-Aldrich

Benzhydrylamine

97%

Sinónimos:

α-Aminodiphenylmethane

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About This Item

Fórmula lineal:
(C6H5)2CHNH2
Número de CAS:
91-00-9
Peso molecular:
183.25
Beilstein/REAXYS Number:
776434
EC Number:
202-032-2
MDL number:
MFCD00008059
UNSPSC Code:
12352100
PubChem Substance ID:
24890969
NACRES:
NA.22

assay

97%

form

liquid

refractive index

n20/D 1.595 (lit.)

bp

295 °C (lit.)

mp

12 °C (lit.)

density

1.063 g/mL at 25 °C (lit.)

SMILES string

NC(c1ccccc1)c2ccccc2

InChI

1S/C13H13N/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13H,14H2

InChI key

MGHPNCMVUAKAIE-UHFFFAOYSA-N

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pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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N A Goud et al.
Journal of bone and mineral research : the official journal of the American Society for Bone and Mineral Research, 6(8), 781-789 (1991-08-01)
We have chemically synthesized the full-length, 84 amino acid, human parathyroid hormone (hPTH) on a greater than 100 mg scale by the Merrifield solid-phase technique of stepwise peptide synthesis using a benzhydrylamine support. The peptide was purified by high-performance liquid
Fang-Kun Deng et al.
Journal of peptide science : an official publication of the European Peptide Society, 16(10), 545-550 (2010-09-09)
Well-characterized resins of high purity are critical for effective solid phase peptide synthesis (SPPS). The quality of commercial (4-methyl)benzhydrylamine-resin (MBHA-resin), used for the synthesis of peptide amides, is not consistent and residual ketone functionalities are frequently present. Such ketone or
Abdul M Seayad et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(18), 5693-5700 (2012-03-23)
A robust heterogeneous self-supported chiral titanium cluster (SCTC) catalyst and its application in the enantioselective imine-cyanation/Strecker reaction is described under batch and continuous processes. One of the major hurdles in the asymmetric Strecker reaction is the lack of availability of
Adrenergic blocking drugs; blocking of excitatory responses to epinephrine and adrenergic nerve stimulation with N-alkyl-N-(2-chloroethyl)-benzhydrylamines.
E R LOEW et al.
The Journal of pharmacology and experimental therapeutics, 97(4), 441-449 (1949-12-01)
Dianne Alewood et al.
Journal of peptide science : an official publication of the European Peptide Society, 16(10), 551-557 (2010-09-24)
The standard p-MBHA resin used during Boc-chemistry synthesis of peptides carrying C-terminal carboxamides is compromised by batch-to-batch variations in its performance. This can cause artificially 'difficult' couplings during peptide chain assembly, which may ultimately lead to failed syntheses given the
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