804320

Potassium 4-ethoxycarbonylbenzoyltrifluoroborate

• Fórmula empírica (notación de Hill): C₁₀H₉BF₃KO₃
• Número de CAS: 1622923-40-3
• Peso molecular: 284.08
• Número MDL: MFCD29037014
• Código UNSPSC: 12352103
• ID de la sustancia en PubChem: 329768861
• NACRES: NA.22

Propiedades

• Formulario: powder
• Nivel de calidad: 100
• mp: 228.00 °C
• cadena SMILES: O=C(B(F)(F)F)C1=CC=C(C(OCC)=O)C=C1.[K]
• InChI: 1S/C10H9BF3O3.K.H/c1-2-17-10(16)8-5-3-7(4-6-8)9(15)11(12,13)14;;/h3-6H,2H2,1H3;;
• Clave InChI: YXYMQBSRJGUKGK-UHFFFAOYSA-N

Descripción

Aplicación

Acyltrifluroborates (KATs) are bench, air, and moisture stable reagents for rapid, chemoselective amide bond formations with hydroxylamines. These amide bond forming reactions proceed under aqueous conditions, without the need for coupling reagents or protecting groups. This product was introduced in collaboration with the Bode Research Group

Otras notas

Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water

Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate (KAT) Amide Formation

Synthesis of Chemically and Configurationally Stable Monofluoro Acylboronates: Effect of Ligand Structure on their Formation; Properties; and Reactivities

Información de seguridad

• Pictogramas: GHS07
• Palabra de señalización: Warning
• Frases de peligro: H315,H319,H335
• Consejos de prudencia: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Clasificaciones de peligro: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Órganos de actuación: Respiratory system
• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable