69868

Magnesium monoperoxyphthalate hexahydrate

technical, ~80% (RT)

• Sinónimos: Magnesium bis(monoperoxyphthalate) hexahydrate, MMPP
• Fórmula lineal: (HO₂CC₆H₄CO₃)₂Mg·6H₂O
• Peso molecular: 494.64
• EC Number: 279-013-0
• MDL number: MFCD00149614
• UNSPSC Code: 12352002
• PubChem Substance ID: 57652217
• NACRES: NA.22

Propiedades

• grade: technical
• assay: ~80% (RT)
• form: powder
• reaction suitability: reagent type: oxidant
• mp: 93 °C (dec.) (lit.)
• SMILES string: O.O.O.O.O.O.OOC(=O)c1ccccc1C(=O)O[Mg]OC(=O)c2ccccc2C(=O)OO
• InChI: 1S/2C8H6O5.Mg.6H2O/c2*9-7(10)5-3-1-2-4-6(5)8(11)13-12;;;;;;;/h2*1-4,12H,(H,9,10);;6*1H2/q;;+2;;;;;;/p-2
• InChI key: WWOYCMCZTZTIGU-UHFFFAOYSA-L

Descripción

General description

Magnesium monoperoxyphthalate hexahydrate is an organic peroxide used in many oxidation reactions. It exhibits non-deflagrating and non-shock-sensitive properties and also used as a surface disinfectant.

Application

Reagent for:

• Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
• Oxidation rections under mild conditions
• Epoxidation of unsaturated steroids
• Synthesis of ring-B oxygenated steroids as anticancer agents

Other Notes

Versatile oxidant soluble in water and the lower alcohols.; Oxidations are carried out in homogenous solution (alcohol, aqueous alcohol) or in a two-phase system under PTC (chloroform-water)

Información de seguridad

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H242,H314,H332
• pcodes: P210 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
• Hazard Classifications: Acute Tox. 4 Inhalation - Eye Dam. 1 - Org. Perox. E - Skin Corr. 1C
• Storage Class: 5.2 - Organic peroxides and self-reacting hazardous materials
• wgk_germany: WGK 1
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves