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461121

Sigma-Aldrich

p-Toluidine

99%

Sinónimos:

4-Aminotoluene, 4-Methylaniline

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About This Item

Fórmula lineal:
CH3C6H4NH2
Número de CAS:
106-49-0
Peso molecular:
107.15
Beilstein/REAXYS Number:
471281
EC Number:
203-403-1
MDL number:
MFCD00007906
UNSPSC Code:
12352100
PubChem Substance ID:
24869813
NACRES:
NA.22

vapor density

3.9 (vs air)

vapor pressure

1 hPa ( 42 °C)
7 hPa ( 68 °C)

assay

99%

form

powder, crystals or chunks

autoignition temp.

899 °F

expl. lim.

6.6 %

bp

200 °C (lit.)

mp

41-46 °C (lit.)

density

0.973 g/mL at 25 °C (lit.)

SMILES string

Cc1ccc(N)cc1

InChI

1S/C7H9N/c1-6-2-4-7(8)5-3-6/h2-5H,8H2,1H3

InChI key

RZXMPPFPUUCRFN-UHFFFAOYSA-N

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General description

p-Toluidine is an aromatic amine. It can be detected in the water samples by homogeneous liquid-liquid extraction followed by ion mobility spectrometry (HLLE-IMS).

Application

p-Toluidine may be used for the determination of hemoglobin adducts of aromatic amines in nonsmokers and smokers of blond- or black-tobacco cigarettes. It may be used for the preparation of bidentate Schiff base ligand, via condensation with salicylaldehyde.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Skin Sens. 1A

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

188.6 °F - closed cup

flash_point_c

87 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Amin Ashori et al.
Bulletin of environmental contamination and toxicology, 94(4), 474-478 (2014-11-28)
In this research, homogeneous liquid-liquid extraction followed by ion mobility spectrometry (HLLE-IMS) with corona discharge ionization source has been developed for the determination of p-toluidine. The analyte was extracted by single-phase extraction in a ternary solvent system and then the
Ruthenium (II) complexes containing bidentate Schiff bases and their antifungal activity.
Dharmaraj N, et al.
Transition Met. Chem. (London), 26(1-2), 105-109 (2001)
M S Bryant et al.
Proceedings of the National Academy of Sciences of the United States of America, 85(24), 9788-9791 (1988-12-01)
Hemoglobin adducts of 15 aromatic amines were determined in nonsmokers and smokers of blond- or black-tobacco cigarettes living in Turin, Italy. The subjects were all males age 55 or less and were representative of the population previously examined in a
Paul G Stevenson et al.
Journal of chromatography. A, 1218(45), 8255-8263 (2011-10-11)
Several simple techniques are presented for the identification of the boundaries of chromatographic peaks. These methods provide a significant reduction in the time needed to perform the rapid, automatic calculation of the central peak moments and to evaluate the quality
Shunji Ito et al.
The Journal of organic chemistry, 70(6), 2285-2293 (2005-03-12)
[reaction: see text] N,N-Di(6-azulenyl)-p-toluidine (1a) and N,N,N',N'-tetra(6-azulenyl)-p-phenylenediamine (2a) and their derivatives with 1,3-bis(ethoxycarbonyl) substituents on each 6-azulenyl group (1b and 2b) were prepared by Pd-catalyzed amine azulenylation and characterized as a study into new aromatic amines for multistage amphoteric redox
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