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Sigma-Aldrich

Tetrakis(acetonitrile)copper(I) hexafluorophosphate

97%

Sinónimos:

Copper(I) tetrakis(acetonitrile) hexafluorophosphate, Cuprous tetrakis(acetonitrile) hexafluorophosphate

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About This Item

Fórmula lineal:
[(CH3CN)4Cu]PF6
Número de CAS:
64443-05-6
Peso molecular:
372.72
Número MDL:
MFCD00064810
Código UNSPSC:
12161600
ID de la sustancia en PubChem:
24861387
NACRES:
NA.22
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Nivel de calidad

100

Ensayo

97%

Formulario

solid

idoneidad de la reacción

core: copper
reagent type: catalyst

mp

160 °C (dec.) (lit.)

cadena SMILES

[Cu+].CC#N.CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F

InChI

1S/4C2H3N.Cu.F6P/c4*1-2-3;;1-7(2,3,4,5)6/h4*1H3;;/q;;;;+1;-1

Clave InChI

GNQXUMGHBSAQBV-UHFFFAOYSA-N

Aplicación

Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.[1]
It can also be used as a copper precursor:
  • For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.[2]
  • To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].[3]
  • To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.[4]
  • For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.[5]

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Gloves, type N95 (US)

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Certificados de análisis (COA)

Lot/Batch Number
0000315505
0000315505
0000242952
0000242952
MKCT6513

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Visite la Librería de documentos

Structural Characterization and Photochemical Properties of Mono-and Bimetallic Cu-Mabiq Complexes.
Stark HS, et al.
Inorganic Chemistry, 28(9), 095705-095705 (2018)
Differential conductance (dI/dV) imaging of a heterojunction-nanorod.
Kundu B, et al.
Nanotechnology, 28(9), 095705-095705 (2017)
Synthesis and characterization of [Cu (NHC)2] X complexes: Catalytic and mechanistic studies of hydrosilylation reactions.
Diez-Gonzalez S, et al.
Chemistry?A European Journal , 14(1), 158-168 (2008)
Two luminescent pseudo-polymorphic cuprous complexes with different optical properties: Synthesis, characterization and TD-DFT calculations.
Tao XD, et al.
Polyhedron, 144(9), 36-43 (2018)
Tetrakis (acetonitrile) copper (I) Hexafluorophosphate as an Efficient Catalyst for the Synthesis of Triazolo [1, 2-a] indazole-1, 3, 8-trione and 2Hindazolo [2, 1-b] phthalazine-trione Derivatives.
Azarifar D, et al.
Letters in Organic Chemistry, 9(2), 128-132 (2012)
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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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