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Merck

290807

Sigma-Aldrich

2-Ethylhexyl methacrylate

98%, contains ~50 ppm monomethyl ether hydroquinone as stabilizer

Sinónimos:

2-EHA, EHMA

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About This Item

Fórmula lineal:
CH2=C(CH3)COOCH2CH(C2H5)(CH2)3CH3
Número de CAS:
Peso molecular:
198.30
Beilstein/REAXYS Number:
1769420
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

vapor density

6.9 (vs air)

assay

98%

contains

~50 ppm monomethyl ether hydroquinone as stabilizer

refractive index

n20/D 1.438 (lit.)

bp

120 °C/18 mmHg (lit.)

density

0.885 g/mL at 25 °C (lit.)

SMILES string

CCCCC(CC)COC(=O)C(C)=C

InChI

1S/C12H22O2/c1-5-7-8-11(6-2)9-14-12(13)10(3)4/h11H,3,5-9H2,1-2,4H3

Inchi Key

WDQMWEYDKDCEHT-UHFFFAOYSA-N

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General description

2-Ethylhexyl methacrylate(EHMA) is a methacrylate ester monomer with low volatility and excellent adhesion to a wide range of substrates. This monomer enhances the flexibility, impact resistance, and toughness of polymers when used in copolymerization. It has good resistance to weathering and helps to enhance the durability and long-term performance of coatings. These copolymers and coatings are applied in the fields of contact lenses, dental restorative materials, and 3D printing.

Application

-Ethylhexyl methacrylate can be used:
  • As a monomer to prepare poly(2-phenoxyethyl methacrylate-co-2-phenoxyethyl acrylate-co-2-ethylhexyl methacrylate) (PPPE) intraocular lenses used in cataract treatment. Polymers with 2% 2-ethylhexyl methacrylate are foldable and showed excellent optical and thermomechanical properties.
  • To prepare copolymer for the surface modification of dental composite resins to control plaque formation. EHMA imparts water resistance and antifouling properties of dental resins.
  • As an internal plasticizer to prepare photo-crosslinked shape memory polymer films used as a photoprintable resins in stereolithography.
  • As a precursor to synthesize hydrogels for fabricating contact lenseswith flexibility, permeability, and comfort.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 1

flash_point_f

197.6 °F - closed cup

flash_point_c

92 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


Certificados de análisis (COA)

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Foldable glistening-free acrylic intraocular lens biomaterials with dual-side heterogeneous surface modification for postoperative endophthalmitis and posterior capsule opacification prophylaxis
Yang Xiang, et al.
Biomacromolecules, 22, 3510-3521 (2021)
3D fabrication of Shape-Memory polymer networks based on coumarin Photo-Dimerization
Belkacem Tarek Benkhaled, et al.
European Polymer Journal, 179, 111570-111570 (2022)
Synthesis and biocompatibility of new contact lenses based on derivatives of 2-hydroxy ethyl meth acrylate and 2-ethyl hexyl methacrylate
Mohammed A Muter
IISRR international journal of research, 3, 1-9 (2015)
Zhao Dang et al.
ACS applied materials & interfaces, 8(45), 31281-31288 (2016-11-04)
The development of stimuli-responsive materials with the ability of controllable oil/water separation is crucial for practical applications. Here, a novel pH responsive nonfluorine-containing copolymer was designed. The copolymer together with silica can be dip-coated on different materials including cotton fabric
In situ surface modification on dental composite resin using 2-methacryloyloxyethyl phosphorylcholine polymer for controlling plaque formation
Jun Koyama, et al.
Materials Science and Engineering, C, 104, 109916-109916 (2019)

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