Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
357405
Zirconium(IV) chloride
≥99.9% trace metals basis
Synonyme(s) :
Tetrachlorozirconium, Zirconium tetrachloride
About This Item
Produits recommandés
Qualité
for analytical purposes
Pression de vapeur
1 mmHg ( 190 °C)
Essai
≥99.9% trace metals basis
Forme
powder
Pertinence de la réaction
reagent type: catalyst
core: zirconium
Impuretés
≤1000.0 ppm Trace Metal Analysis
Température de transition
sublimation point 331 °C
Densité
2.8 g/mL at 25 °C (lit.)
Application(s)
battery manufacturing
Chaîne SMILES
Cl[Zr](Cl)(Cl)Cl
InChI
1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4
Clé InChI
DUNKXUFBGCUVQW-UHFFFAOYSA-J
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Application
- electrophilic addition reaction of indole with aldehydes/ketones to form bis(indolyl)methanes. electrophilic amination of activated arenes,
- transthioacetylization of acetals,
- deoxygenation of heterocyclic-N-oxides,
- reduction of nitro compounds,
- conversion of carbonyl compounds to 1,3-oxathiolanes,
- Biginelli reaction for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones,[1]
- direct amide coupling of non activated carboxylic acids and amines,[2]
- synthesis of quinoxalines and pyrido[2,3-b]pyrazines,[3]
- deprotection of t-butyldimethylsilyl (TBDMS) ethers.[4]
Mention d'avertissement
Danger
Mentions de danger
Classification des risques
Met. Corr. 1 - Skin Corr. 1B
Risques supp
Code de la classe de stockage
8A - Combustible corrosive hazardous materials
Classe de danger pour l'eau (WGK)
WGK 3
Point d'éclair (°F)
Not applicable
Point d'éclair (°C)
Not applicable
Équipement de protection individuelle
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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