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8.08913

Sigma-Aldrich

Zirconium(IV) chloride

anhydrous, for synthesis

Synonyme(s) :

Zirconium(IV) chloride, Zirconium tetrachloride

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About This Item

Formule empirique (notation de Hill):
Cl4Zr
Numéro CAS:
Poids moléculaire :
233.04
Numéro MDL:
Code UNSPSC :
12352302
Numéro de classement CE :
233-058-2
Nomenclature NACRES :
NA.22
Forme:
crystals
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Pression de vapeur

1.3 hPa ( 190 °C)

Niveau de qualité

Forme

crystals

Puissance

1688 mg/kg LD50, oral (Rat)

pH

<1 (20 °C in H2O, saturated aqueous solution)

Pf

437 °C

Densité

2.80 g/cm3 at 15 °C

Masse volumique apparente

1200 kg/m3

Température de stockage

2-30°C

Chaîne SMILES 

[Zr](Cl)(Cl)(Cl)Cl

InChI

1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4

Clé InChI

DUNKXUFBGCUVQW-UHFFFAOYSA-J

Description générale

Zirconium(IV) chloride is a Lewis acid catalyst, widely used in organic synthesis for the preparation of useful key intermediates. Since it is a stable and environmentally friendly catalyst used in various chemical reactions such as carbon-carbon bond formation reactions, reduction reactions, protection, and deprotection reactions.[1]

Application

Zirconium(IV) chloride can be used as a catalyst to synthesize:
  • β-amino alcohols by ring-opening of epoxides with aromatic amines.[2]
  • β-amino analogs via conjugate addition of aliphatic amines to α,β-unsaturated ester, nitriles, and ketones.[3]
  • 1,3,4-oxadiazole derivatives by cyclodehydration of 1,2-diacylhydrazines.[4]
  • 3,4-Dihydropyrimidinone derivatives via Biginelli condensation reaction of aromatic aldehyde, β-ketoester, and urea.[5]

Remarque sur l'analyse

Assay (argentometric): ≥ 98.0 %
Hafnium (Hf): ≤ 40 ppm
Identity (ICP-OES): passes test

Pictogrammes

Corrosion

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Met. Corr. 1 - Skin Corr. 1B

Risques supp

Code de la classe de stockage

8B - Non-combustible, corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


Certificats d'analyse (COA)

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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