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Merck

O1858

Sigma-Aldrich

1-Octadecanethiol

98%

Sinónimos:

Mercaptan C18, Octadecyl mercaptan, Stearyl mercaptan

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About This Item

Fórmula lineal:
CH3(CH2)17SH
Número de CAS:
Peso molecular:
286.56
Beilstein:
1811934
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de la sustancia en PubChem:
NACRES:
NA.23
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Nivel de calidad

Ensayo

98%

bp

204-210 °C/11 mmHg (lit.)

mp

30-33 °C (lit.)

densidad

0.847 g/mL at 25 °C (lit.)

cadena SMILES

CCCCCCCCCCCCCCCCCCS

InChI

1S/C18H38S/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19/h19H,2-18H2,1H3

Clave InChI

QJAOYSPHSNGHNC-UHFFFAOYSA-N

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Descripción general

1-Octadecanethiol (ODT) is an alkanethiol with a long carbon chain mainly used as a self-assembled monolayer (SAM) for surface modification of a wide range of materials. It facilitates superhydrophobicity with high wettability and low surface energy.[1][2]

Aplicación

ODT is used in the surface modification of gold nanoparticle (AuNPs)/Nickel (Ni) foam conjugate for the preparation of a 3D surface enhanced Raman spectroscopy(SERS) substrate for the detection of organic pollutants.[3] It may also be used enhance the superhydrophobic properties for different materials like nano-sized copper films,[4] graphene and silica for different applications like mercury detection and electrochemical analysis.[5][1]

Pictogramas

Exclamation markEnvironment

Palabra de señalización

Warning

Frases de peligro

Clasificaciones de peligro

Aquatic Acute 1 - Skin Irrit. 2

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

dust mask type N95 (US), Eyeshields, Gloves


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Certificados de análisis (COA)

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Electrochemical investigation of dynamic interfacial processes at 1-octadecanethiol-modified copper electrodes in halide-containing solutions.
Ma HY, et al.
Electrochimica Acta, 48(28), 4277-4289 (2003)
Fabrication of super-hydrophobic nano-sized copper films by electroless plating.
Liu X, et al.
Thin Solid Films, 518(14), 3731-3734 (2010)
Three-dimensional superhydrophobic surface-enhanced Raman spectroscopy substrate for sensitive detection of pollutants in real environments.
Zhao H, et al.
Journal of Material Chemistry A, 3(8), 4330-4337 (2015)
Adhesion and friction studies of microsphere-patterned surfaces in contact with atomic force microscopy colloidal probe.
Zhang X, et al.
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 401(28), 90-96 (2012)
Jimin Yao et al.
Advanced materials (Deerfield Beach, Fla.), 22(10), 1102-1110 (2010-04-20)
Plasmonic crystals fabricated with precisely controlled arrays of subwavelength metal nanostructures provide a promising platform for sensing and imaging of surface binding events with micrometer spatial resolution over large areas. Soft nanoimprint lithography provides a robust, cost-effective method for producing

Artículos

Self-assembled monolayers (SAMs) have diverse applications; article compares benefits of alkylthiolates on gold SAM systems.

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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