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Merck
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B56501

Sigma-Aldrich

4-Bromoanisole

≥99.0%

Sinónimos:

1-Bromo-4-methoxybenzene

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About This Item

Fórmula lineal:
BrC6H4OCH3
Número de CAS:
104-92-7
Peso molecular:
187.03
Beilstein/REAXYS Number:
1237590
EC Number:
203-252-1
MDL number:
MFCD00000097
UNSPSC Code:
12352100
PubChem Substance ID:
24891850
NACRES:
NA.22

assay

≥99.0%

form

liquid

refractive index

n20/D 1.564 (lit.)

bp

223 °C (lit.)

mp

9-10 °C (lit.)

density

1.494 g/mL at 25 °C (lit.)

SMILES string

COc1ccc(Br)cc1

InChI

1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3

InChI key

QJPJQTDYNZXKQF-UHFFFAOYSA-N

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Categorías relacionadas

General description

4-Bromoanisole is a useful brominating reagent. It is formed as reaction product in the reaction between HOBr and anisole. Suzuki coupling of 4-bromoanisole with phenylboronic acid catalyzed by palladium pincer complexes has been studied. Heck Reaction of 4-bromoanisole with ethyl acrylates in room-temperature ionic liquids is reported to afford ethyl 4-methoxycinnamate.

Application

4-Bromoanisole was used in the synthesis of aryl 1,3-diketones.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302,H315

Hazard Classifications

Acute Tox. 4 Oral - Skin Irrit. 2

Storage Class

10 - Combustible liquids

wgk_germany

WGK 2

flash_point_f

201.2 °F

flash_point_c

94 °C

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Anisole analytical standard

Supelco

96109

Anisole

4′-Bromoacetophenone 98%

Sigma-Aldrich

B56404

4′-Bromoacetophenone

4-Methoxyphenylboronic acid ≥95.0%

Sigma-Aldrich

417599

4-Methoxyphenylboronic acid

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