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757136

Sigma-Aldrich

Lithium bis(oxalato)borate

greener alternative

Sinónimos:

LiBOB, Lithium bis(ethanedioato)borate, Lithium bis(oxalate)borate

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About This Item

Fórmula lineal:
LiB(C2O4)2
Número de CAS:
244761-29-3
Peso molecular:
193.79
Número MDL:
MFCD07776904
Código UNSPSC:
26111700
ID de la sustancia en PubChem:
329766649
NACRES:
NA.23

Formulario

powder or crystals

Nivel de calidad

100

características de los productos alternativos más sostenibles

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>300 °C (lit.)

aplicaciones

battery manufacturing

categoría alternativa más sostenible

Enabling,

cadena SMILES

[Li+].O=C1O[B-]2(OC1=O)OC(=O)C(=O)O2

InChI

1S/C4BO8.Li/c6-1-2(7)11-5(10-1)12-3(8)4(9)13-5;/q-1;+1

Clave InChI

NVQAYVUCVASGDK-UHFFFAOYSA-N

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Descripción general

Lithium bis(oxalato)borate (LiBOB) is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Aplicación

LiBOB is a novel boron based Li salt electrolyte material for Li ion batteries. It is environmentally friendly with good film forming property and high thermal stability and is compatible with a variety of anodes and metal oxide cathode.
LiBOB is a thermally stable electrolyte that can be used to protect graphite-based anode materials in lithium-ion batteries. It shows good electrochemical performance with a discharge capacity retention of ~ 83%.

Información legal

Product of Albemarle US Inc

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Pictogramas

CorrosionExclamation mark
GHS05,GHS07

Palabra de señalización

Danger

Frases de peligro

H302,H317,H318

Clasificaciones de peligro

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1A

Código de clase de almacenamiento

13 - Non Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 1

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Certificados de análisis (COA)

Lot/Batch Number
MKCX1621
MKCR2765
MKCM2470
MKCJ2299
MKCG4950

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Lithium bis (oxalato) borate stabilizes graphite anode in propylene carbonate
Xu K, et al.
Electrochemical and Solid-State Letters, 5(11), A259-A259 (2002)
Wengao Zhao et al.
ChemSusChem, 11(13), 2211-2220 (2018-05-03)
The long-term cycling performance, rate capability, and voltage stability of lithium (Li) metal batteries with LiNi0.76 Mn0.14 Co0.10 O2 (NMC76) cathodes is greatly enhanced by lithium bis(oxalato)borate (LiBOB) additive in the LiPF6 -based electrolyte. With 2 % LiBOB in the electrolyte
R Verrelli et al.
Physical chemistry chemical physics : PCCP, 19(38), 26435-26441 (2017-09-26)
Layered MgMoN
Shoichi Matsuda et al.
Scientific reports, 9(1), 6211-6211 (2019-04-19)
Data-driven material discovery has recently become popular in the field of next-generation secondary batteries. However, it is important to obtain large, high quality data sets to apply data-driven methods such as evolutionary algorithms or Bayesian optimization. Combinatorial high-throughput techniques are
Jenny Strehlau et al.
Analytical and bioanalytical chemistry, 409(26), 6123-6131 (2017-08-05)
A novel method based on liquid-liquid extraction with subsequent gas chromatography separation and mass spectrometric detection (GC-MS) for the quantification of organic carbonates in cell culture materials is presented. Method parameters including the choice of extraction solvent, of extraction method
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