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757136

Sigma-Aldrich

Lithium bis(oxalato)borate

greener alternative

Sinónimos:

LiBOB, Lithium bis(ethanedioato)borate, Lithium bis(oxalate)borate

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About This Item

Fórmula lineal:
LiB(C2O4)2
Número de CAS:
244761-29-3
Peso molecular:
193.79
Número MDL:
MFCD07776904
Código UNSPSC:
26111700
ID de la sustancia en PubChem:
329766649
NACRES:
NA.23

Formulario

powder or crystals

características de los productos alternativos más sostenibles

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>300 °C (lit.)

aplicaciones

battery manufacturing

categoría alternativa más sostenible

Enabling,

cadena SMILES

[Li+].O=C1O[B-]2(OC1=O)OC(=O)C(=O)O2

InChI

1S/C4BO8.Li/c6-1-2(7)11-5(10-1)12-3(8)4(9)13-5;/q-1;+1

Clave InChI

NVQAYVUCVASGDK-UHFFFAOYSA-N

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Descripción general

Lithium bis(oxalato)borate (LiBOB) is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Aplicación

LiBOB is a novel boron based Li salt electrolyte material for Li ion batteries. It is environmentally friendly with good film forming property and high thermal stability and is compatible with a variety of anodes and metal oxide cathode.
LiBOB is a thermally stable electrolyte that can be used to protect graphite-based anode materials in lithium-ion batteries. It shows good electrochemical performance with a discharge capacity retention of ~ 83%.

Información legal

Product of Albemarle US Inc

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Pictogramas

CorrosionExclamation mark
GHS05,GHS07

Palabra de señalización

Danger

Frases de peligro

H302,H317,H318

Clasificaciones de peligro

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1A

Código de clase de almacenamiento

13 - Non Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 1

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Certificados de análisis (COA)

Lot/Batch Number
MKCX1621
MKCR2765
MKCM2470
MKCJ2299
MKCG4950

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Snehashis Choudhury et al.
Nature communications, 10(1), 4398-4398 (2019-09-29)
Electrochemical cells based on alkali metal anodes are receiving intensive scientific interest as potentially transformative technology platforms for electrical energy storage. Chemical, morphological, mechanical and hydrodynamic instabilities at the metal anode produce uneven metal electrodeposition and poor anode reversibility, which, are among the many
Surface layer formed on silicon thin-film electrode in lithium bis (oxalato) borate-based electrolyte
Choi N, et al.
Journal of Power Sources, 172(1), 404-409 (2007)
On the electrochemical and thermal behavior of lithium bis (oxalato) borate (LiBOB) solutions
Larush-Asraf L, et al.
Journal of Power Sources, 174(2), 400-407 (2007)
Lithium bis (oxalato) borate stabilizes graphite anode in propylene carbonate
Xu K, et al.
Electrochemical and Solid-State Letters, 5(11), A259-A259 (2002)
R Verrelli et al.
Physical chemistry chemical physics : PCCP, 19(38), 26435-26441 (2017-09-26)
Layered MgMoN
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