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Merck

642452

Sigma-Aldrich

Molybdenum(V) chloride

anhydrous, powder, 99.99% trace metals basis (excluding W)

Sinónimos:

Molybdenum pentachloride, Molybdenum(5+) chloride

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About This Item

Fórmula lineal:
MoCl5
Número de CAS:
Peso molecular:
273.21
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

grade

anhydrous

vapor pressure

1.75 mmHg ( 25 °C)
131 mmHg ( 250 °C)

assay

99.99% trace metals basis (excluding W)

form

powder

impurities

≤150.0 ppm Trace Metal Analysis

bp

268 °C (lit.)

mp

194 °C (lit.)

density

2.928 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

Cl[Mo](Cl)(Cl)(Cl)Cl

InChI

1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5

InChI key

GICWIDZXWJGTCI-UHFFFAOYSA-I

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General description

Molybdenum(V) chloride, also called as molybdenum pentachloride is a Lewis acid with high oxidation potential. It is widely used as a catalyst in the field of organic synthesis and polymer chemistry. It is also used as a chemical vapor deposition precursor.

Application

Molybdenum(V) chloride can be used:
  • As a catalyst for amidation of secondary benzyl alcohols.
  • As a precursor to fabricate MoS2 thin films by atomic layer deposition method.
  • As a primary catalyst for coordination polymerization of butadiene.
  • To fabricate superior anode materials for Na-ion and Li-ion batteries.
  • As a dual-function redox mediator for Li–O2 batteries to overcome thehigh polarization and low energy density issues.

For use with

Referencia del producto
Descripción
Precios

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Los clientes también vieron

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m-Cresol-substituted triethyl aluminum/MoCl5/TBP catalytic system for coordination polymerization of butadiene
Peipei Li, et al.
Iranian Polymer Journal, 27, 537-544 (2018)
Atomic layer deposition of a MoS2 film
Lee Kheng Tan, et al.},
Nanoscale, 6, 10584-10588 (2014)
Molybdenum(V) chloride-catalyzed amidation of secondary benzyl alcohols with sulfonamides and carbamates
Ch. Raji Reddy, et al.},
Tetrahedron Letters, 48, 7169-7172 (2007)
Towards high-volumetric performance of Na/Li-ion batteries: A better anode material with molybdenum pentachloride--graphite intercalation compounds (MoCl 5--GICs
Zheng Li, et al.
Journal of Materials Chemistry, 8, 2430-2438 (2020)
MoCl5 as a dual-function redox mediator for Li-O2 batteries
Xin-Gai Wang, et al.
Journal of Materials Chemistry, 7, 14239-14243 (2019)

Artículos

The diversity of applications and nanostructured materials accessible using ultrasonic spray methods are highlighted in this article.

Ultrasonic spray pyrolysis produces scalable nanomaterials like metal oxides and quantum dots for diverse applications.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Protocolos

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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