588466

Methyl α-bromoacrylate

95%

• Fórmula empírica (notación de Hill): C₄H₅BrO₂
• Número de CAS: 4519-46-4
• Peso molecular: 164.99
• MDL number: MFCD08276754
• UNSPSC Code: 12162002
• PubChem Substance ID: 24881219
• NACRES: NA.23

Propiedades

• assay: 95%
• bp: 70-75 °C/48 mmHg (lit.)
• density: 1.556 g/mL at 25 °C (lit.)
• storage temp.: −20°C
• SMILES string: COC(=O)C(Br)=C
• InChI: 1S/C4H5BrO2/c1-3(5)4(6)7-2/h1H2,2H3
• InChI key: HVJXPDPGPORYKY-UHFFFAOYSA-N

Descripción

Application

Methyl α-bromoacrylate can undergo radical copolymerization with vinyl triacetoxysilane (VTAS) in the presence of azobisisobutyronitrile as the initiator. Dibromocyclopropanation of methyl α-bromoacrylate can yield methyl 1,1,2-tribromocyclopropanecarboxylate. It may be reduced with zinc dust and deuterium oxide to synthesize. Methyl acrylate-α-d with a high isotopic purity. These may undergo conjugate addition with methoxide, thiolates, oxime anions, hydrazones and EtZnCl to afford ester enolates.

Información de seguridad

• pictograms: GHS02,GHS07
• signalword: Warning
• hcodes: H226,H315,H319,H335
• pcodes: P210 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 134.6 °F - closed cup
• flash_point_c: 57 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter