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44570

Dowtherm® A

eutectic mixture of 26.5% diphenyl + 73.5% diphenyl oxide

Sinónimos:

Diphyl

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Talla/SKUDisponibilidadPrecio
1 L
Comprobar disponibilidad del carrito
$214.000

Acerca de este artículo

NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:

$214.000


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Quality Segment

refractive index

n20/D 1.590

functional group

phenoxy, phenyl

SMILES string

c1ccc(cc1)-c2ccccc2.O(c3ccccc3)c4ccccc4

InChI

1S/C12H10O.C12H10/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;1-3-7-11(8-4-1)12-9-5-2-6-10-12/h1-10H;1-10H

InChI key

MHCVCKDNQYMGEX-UHFFFAOYSA-N

General description

Dowtherm® A is a thermally stable organic heat transfer fluid composed of a eutectic mixture of highly stable compounds, biphenyl, and diphenyl oxide. Dowtherm® A is suitable for high-temperature heat transfer applications up to 400 °C. This fluid can be used in both liquid and vapor phase systems.

Application

Dowtherm® A can be used as a high boiling solvent in cyclization reactions. For example, it is used to synthesize:      
  • 1-Hydroxy-5-methoxy-1,2-dihydrobenzo[f][2,7]naphthyridines from 2-chloro-3-formyl quinolines.     
  • Isoindolinone derivatives via intramolecular Diels–Alder cycloaddition reactions of substituted pyridazines.
  • Phosphorylated azaheterocycles from 2-diethoxyphosphoryl-3-methoxyacrylate via intramolecular cyclizations under thermal conditions.

Legal Information

DOWTHERM is a registered trademark of The Dow Chemical Company or an affiliated company of Dow

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Este artículo
P24101389196230138
description

eutectic mixture of 26.5% diphenyl + 73.5% diphenyl oxide

description

ReagentPlus®, 99%

description

98%

description

98%

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

100

refractive index

n20/D 1.590

refractive index

n20/D 1.579 (lit.)

refractive index

-

refractive index

n20/D 1.425 (lit.)

functional group

phenoxy, phenyl

functional group

phenoxy

functional group

phenyl, phosphine, ether

functional group

-


Órganos diana

Respiratory system

Punto de inflamación (°F)

Not applicable

Punto de inflamación (°C)

Not applicable

EPI (equipos de protección individual)

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Palabra de advertencia

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Clase de almacenamiento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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