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Sigma-Aldrich

Tetrakis(hydroxymethyl)phosphonium chloride solution

Tetrakis(hydroxymethyl)phosphonium chloride solution
1 of 1 reviewers received a sample product or took part in a promotion

80% in H2O

Sinónimos:

THPC solution

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100 ML
$65.600
500 ML
$208.000

$65.600

Fecha estimada de envío13 de mayo de 2025

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100 ML
$65.600
500 ML
$208.000

About This Item

Fórmula lineal:
(HOCH2)4PCl
Número de CAS:
124-64-1
Peso molecular:
190.56
Beilstein:
3631669
Número MDL:
MFCD00031687
Código UNSPSC:
12352101
ID de la sustancia en PubChem:
24865276
NACRES:
NA.22

$65.600

Fecha estimada de envío13 de mayo de 2025

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Formulario

liquid

concentración

80% in H2O

índice de refracción

n20/D 1.512

densidad

1.341 g/mL at 25 °C

cadena SMILES

[Cl-].OC[P+](CO)(CO)CO

InChI

1S/C4H12O4P.ClH/c5-1-9(2-6,3-7)4-8;/h5-8H,1-4H2;1H/q+1;/p-1

Clave InChI

AKXUUJCMWZFYMV-UHFFFAOYSA-M

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Categorías relacionadas

Aplicación

Tetrakis(hydroxymethyl)phosphonium chloride solution (80% in H2O) has been used as a reducing agent and stabilizing ligand for the synthesis of gold nanoparticles (AuNPs) from gold(III) chloride trihydrate (HAuCl4.3H2O).[1][2] It is a tetra-functional, amine-reactive, aqueous crosslinker that can be used for tuning the properties of protein-based hydrogels for 3D cell encapsulation applications.[3]

Palabra de señalización

Danger

Clasificaciones de peligro

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Repr. 1B - Skin Corr. 1B - Skin Sens. 1

Código de clase de almacenamiento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
WXBF4211V
WXBF3233V
WXBF4791V
WXBD6276V
WXBD4945V

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Facile preparation of water-soluble fluorescent gold nanoclusters for cellular imaging applications.
Shang L, et al.
Nanoscale, 3(5), 2009-2014 (2011)
Beyond gold: rediscovering tetrakis-(hydroxymethyl)-phosphonium chloride (THPC) as an effective agent for the synthesis of ultra-small noble metal nanoparticles and Pt-containing nanoalloys
Hueso J L, et al.
Royal Society of Chemistry Advances, 3(26), 10427-10433 (2013)
Baris Karakullukcu et al.
Journal of biophotonics, 4(10), 740-751 (2011-08-24)
The objective quantitative monitoring of light, oxygen, and photosensitizer is challenging in clinical photodynamic therapy settings. We have previously developed fluorescence differential path-length spectroscopy (FDPS), a technique that utilizes reflectance spectroscopy to monitor microvascular oxygen saturation, blood volume fraction, and
Cindy Chung et al.
Biomacromolecules, 13(12), 3912-3916 (2012-11-16)
Native tissues provide cells with complex, three-dimensional (3D) environments comprised of hydrated networks of extracellular matrix proteins and sugars. By mimicking the dimensionality of native tissue while deconstructing the effects of environmental parameters, protein-based hydrogels serve as attractive, in vitro
D J Ball et al.
Journal of photochemistry and photobiology. B, Biology, 45(1), 28-35 (1998-11-20)
Three substituted zinc (II) phthalocyanines (one anionic, one cationic and one hydrophobic) have been compared to two clinically used photosensitisers, 5,10,15,20-tetra (m-hydroxyphenyl) chlorin (mTHPC) and polyhaematoporphyrin (PHP), as potential agents for photodynamic therapy (PDT). Oxygen-consumption experiments, performed to follow the
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Questions

1–3 of 3 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. Is this chemical cationic or anionic? Thank you

    1 answer

    1. For this compound, the Tetrakis(hydroxymethyl)phosphonium ion is the cation, and the chloride ion is the anion. Since the Tetrakis(hydroxymethyl)phosphonium ion is the more "interesting" part of this compound, one might see it referred to in the chemical literature as a cationic crosslinker or a cationic ligand.

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Reviews

1 of 1 reviewers received a sample product or took part in a promotion

Active Filters

  1. Milwaukee Wisconsin
    • Review 1
    • Votes 0
    5 out of 5 stars.

    Great reagent for synthesis

    This product is very versatile for making so many derivatives. It is one of my favorite phosphines. Affordable and intriguing, like a fine wine.

    Helpful?

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