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Merck

282316

Sigma-Aldrich

Perfluoro-1,3-dimethylcyclohexane

technical grade, 80%

Sinónimos:

Decafluoro-1,3-bis(trifluoromethyl)cyclohexane, Hexadecafluoro-1,3-dimethylcyclohexane, Hexadecafluoro-1,3-dimethylcyclohexane (cis+trans)

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About This Item

Fórmula lineal:
C6F10(CF3)2
Número de CAS:
Peso molecular:
400.06
Beilstein/REAXYS Number:
2064147
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

Quality Level

vapor density

14 (vs air)

assay

80%

form

liquid

refractive index

n20/D 1.3 (lit.)

bp

101-102 °C (lit.)

mp

−55 °C (lit.)

density

1.828 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(C(F)(F)F)C1(F)F

InChI

1S/C8F16/c9-1(7(19,20)21)3(11,12)2(10,8(22,23)24)5(15,16)6(17,18)4(1,13)14

InChI key

LOQGSOTUHASIHI-UHFFFAOYSA-N

General description

Quenching of the second excited singlet state of xanthione in inert, nonpolar perfluoro-1,3-dimethylcyclohexane has been studied using picosecond time-resolved fluorescence decay methods.

Application

Perfluoro-1,3-dimethylcyclohexane has been used in:
  • the preparation of amorphous fluorocarbon films by plasma polymerization
  • hydroformylation of linear terminal alkenes using rhodium based catalysts under fluorous biphasic conditions in the presence and absence of toluene

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Journal of Vacuum Science & Technology. A, Vacuum, Surfaces, And Films, 16(4), 2120-2124 (1998)
Hydroformylation in perfluorinated solvents; improved selectivity, catalyst retention and product separation.
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Tetrahedron, 58(20), 3901-3910 (2002)
Transient effects in the fluorescence quenching of xanthione in perfluoro-1, 3-dimethylcyclohexane.
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