The 10G and 25G sizes are packaged in amber glass bottles in an overpack safety can. The 100G, 500G, and 1KG sizes are packaged in polyamide bags, then placed in a re-sealable paint-style can, followed by an overpack safety can. Currently, this is the packaging schematic for all materials, globally.
199877
Lithium aluminum hydride
powder, reagent grade, 95%
Sinónimos:
LAH, Lithium alanate, Lithium tetrahydroaluminate
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10 G
$84.100
25 G
$131.000
100 G
$211.000
500 G
$517.000
1 KG
$893.000
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10 G
$84.100
25 G
$131.000
100 G
$211.000
500 G
$517.000
1 KG
$893.000
About This Item
Fórmula lineal:
LiAlH4
Número de CAS:
Peso molecular:
37.95
Número CE:
Número MDL:
Código UNSPSC:
26111700
ID de la sustancia en PubChem:
NACRES:
NA.22
Productos recomendados
grado
reagent grade
Nivel de calidad
Ensayo
95%
Formulario
powder
idoneidad de la reacción
reagent type: reductant
características de los productos alternativos más sostenibles
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
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mp
125 °C (dec.) (lit.)
categoría alternativa más sostenible
cadena SMILES
[Li].[AlH3]
InChI
1S/Al.Li.4H/q-1;+1;;;;
Clave InChI
OCZDCIYGECBNKL-UHFFFAOYSA-N
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Descripción general
Atomic number of base material: 3
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.
Aplicación
Lithium aluminum hydride (LiAlH4) is an effective reducing agent that can be used in chemical synthesis to reduce esters, carboxylic acids, acyl chlorides, aldehydes, epoxides, and ketones into the corresponding alcohols. In addition, amide, nitro, nitrile, imine, oxime, and azide compounds are converted into amines.[1][2]
LiAlH4 is a promising substance for hydrogen storage applications. Its properties include high gravimetric and volumetric hydrogen densities [3][4][5]. It can also be used as a reducing agent in the preparation of reduced graphene oxide (rGO).[6]
LiAlH4 is a promising substance for hydrogen storage applications. Its properties include high gravimetric and volumetric hydrogen densities [3][4][5]. It can also be used as a reducing agent in the preparation of reduced graphene oxide (rGO).[6]
Palabra de señalización
Danger
Frases de peligro
Consejos de prudencia
Clasificaciones de peligro
Eye Dam. 1 - Skin Corr. 1A - Water-react 1
Código de clase de almacenamiento
4.3 - Hazardous materials which set free flammable gases upon contact with water
Clase de riesgo para el agua (WGK)
WGK 1
Punto de inflamabilidad (°F)
Not applicable
Punto de inflamabilidad (°C)
Not applicable
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Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.
Lithium Aluminum Hydride
Paquette LA, et al.
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
Synthesis and characterization of lithium aminoborohydrides: A new class of powerful reducing agents
Fisher GB, et al.
Tetrahedron Letters, 33(32), 4533-4536 (1992)
Lithium aluminum hydride as reducing agent for chemically reduced graphene oxides
Ambrosi A, et al.
Chemistry of Materials, 24(12), 2292-2298 (2012)
A first-principles study of the electronic structure and stability of a lithium aluminum hydride for hydrogen storage
Song Y, et al.
The Journal of Physical Chemistry B, 110(13), 6906-6910 (2006)
Reversible hydrogen storage via titanium-catalyzed LiAlH4 and Li3AlH6
Chen J, et al.
The Journal of Physical Chemistry B, 105(45), 11214-11220 (2001)
Artículos
Mechanochemical Effect of Severe Plastic Deformations: Metal Alloys, Hydrides and Molecular Solids
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Why is Lithium Aluminum Hydride, #199877, not packaged in a rigid container in the USA? The web site says it is packaged in plastic bags in Europe. The sample we received was in a plastic bag (in an outer can).
1 answer-
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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How is shipping temperature determined? And how is it related to the product storage temperature?
1 answer-
Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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