Passa al contenuto
Merck

Dispersion of titanate nanotubes for nanomedicine: comparison of PEI and PEG nanohybrids.

Dalton transactions (Cambridge, England : 2003) (2014-11-20)
Anne-Laure Papa, Julien Boudon, Vanessa Bellat, Alexis Loiseau, Harender Bisht, Fadoua Sallem, Rémi Chassagnon, Véronique Bérard, Nadine Millot
ABSTRACT

In the present study, we report the dispersion of titanate nanotubes (TiONts) via polymer grafting (PolyEthylene Glycol, PEG) or polymer adsorption (polyethylene imine, PEI) where different TiONts/polymer ratios have been investigated. The TiONts/PEI and TiONts/PEG nanohybrids were characterized by scanning and transmission electron microscopy as well as by zeta potential measurements in order to determine both their dispersion state and stability in water (at different pH for zetametry). The nature of the chemical bonds at the surface of these nanohybrids was investigated by Fourier-transformed infrared (FTIR) spectroscopy while the grafting densities of PEG on the nanotubes were quantified by thermogravimetric analyses (TGA). The nanohybrids reported here are promising tools for biotechnology applications due to their tubular morphology, their very good dispersion in water and the reactivity of their surface.

MATERIALI
N° Catalogo
Marchio
Descrizione del prodotto

Sigma-Aldrich
Tetraidrofurano, inhibitor-free, suitable for HPLC, ≥99.9%
Sigma-Aldrich
Acido cloridrico, ACS reagent, 37%
Sigma-Aldrich
Sodio idrossido, ACS reagent, ≥97.0%, pellets
Sigma-Aldrich
Acido cloridrico, ACS reagent, 37%
Sigma-Aldrich
Sodio idrossido, reagent grade, ≥98%, pellets (anhydrous)
Sigma-Aldrich
Tetraidrofurano, contains 250 ppm BHT as inhibitor, ACS reagent, ≥99.0%
Sigma-Aldrich
Idrossido di sodio, 50% in H2O
Sigma-Aldrich
Cloruro di idrogeno, 4.0 M in dioxane
Sigma-Aldrich
Esano, suitable for HPLC, ≥97.0% (GC)
Sigma-Aldrich
Esano, ReagentPlus®, ≥99%
Sigma-Aldrich
Esano, suitable for HPLC, ≥95%
Sigma-Aldrich
(3-amminopropil)trimetossisilano, 99%
Sigma-Aldrich
Tiazolil blu tetrazolio bromuro, 98%
Sigma-Aldrich
Idrossido di sodio, BioUltra, for molecular biology, 10 M in H2O
Sigma-Aldrich
Acido cloridrico, 1.0 N, BioReagent, suitable for cell culture
Sigma-Aldrich
Tiazolil blu tetrazolio bromuro, powder, BioReagent, suitable for cell culture, suitable for insect cell culture, ≥97.5% (HPLC)
Sigma-Aldrich
Cloruro di calcio, BioUltra, for molecular biology, ~1 M in H2O
Sigma-Aldrich
Esano, Laboratory Reagent, ≥95%
Sigma-Aldrich
Sodio idrossido, BioXtra, ≥98% (acidimetric), pellets (anhydrous)
Sigma-Aldrich
Idrossido di sodio, 1.0 N, BioReagent, suitable for cell culture
Sigma-Aldrich
Acido cloridrico, meets analytical specification of Ph. Eur., BP, NF, fuming, 36.5-38%
Sigma-Aldrich
Esano, puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99% (GC)
Sigma-Aldrich
Sodio idrossido, puriss., meets analytical specification of Ph. Eur., BP, NF, E524, 98-100.5%, pellets
Sigma-Aldrich
Acido cloridrico, 37 wt. % in H2O, 99.999% trace metals basis
Sigma-Aldrich
Sodio idrossido, reagent grade, 97%, powder
Sigma-Aldrich
Esano, HPLC Plus, for HPLC, GC, and residue analysis, ≥95%
Sigma-Aldrich
Acido cloridrico, 36.5-38.0%, BioReagent, for molecular biology
Sigma-Aldrich
Cloruro di idrogeno, 2.0 M in diethyl ether
Sigma-Aldrich
Acido cloridrico, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., fuming, ≥37%, APHA: ≤10
Sigma-Aldrich
Sodio idrossido, pellets, semiconductor grade, 99.99% trace metals basis