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676926

Sigma-Aldrich

2-butanone

ACS reagent, ≥99.0%

Sinonimo/i:

Etil metil chetone, MEK, Metil etil chetone

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About This Item

Formula condensata:
C2H5COCH3
Numero CAS:
Peso molecolare:
72.11
Beilstein:
741880
Numero CE:
Numero MDL:
Codice UNSPSC:
12352115
eCl@ss:
39021202
ID PubChem:
NACRES:
NA.21

Grado

ACS reagent

Densità del vapore

2.49 (vs air)

Tensione di vapore

71 mmHg ( 20 °C)

Saggio

≥99.0%

Forma fisica

liquid

Temp. autoaccensione

960 °F

Limite di esplosione

10.1 %

Impurezze

≤0.0005 meq/g Titr. acid
≤0.20% water

Residuo dopo evaporazione

≤0.0025%

Colore

APHA: ≤15

Indice di rifrazione

n20/D 1.379 (lit.)

P. eboll.

80 °C (lit.)

Punto di fusione

−87 °C (lit.)

Densità

0.805 g/mL at 25 °C (lit.)

Stringa SMILE

CC(CC)=O

InChI

1S/C4H8O/c1-3-4(2)5/h3H2,1-2H3
ZWEHNKRNPOVVGH-UHFFFAOYSA-N

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Descrizione generale

2-Butanone is a ketone. Physical properties of the solutions of 1-n-butyl-3-methylimidazolium tetrafluoroborate (ionic liquid) in various organic solvents (acetonitrile, dichloromethane, 2-butanone and N,N-dimethylformamide) has been studied. Viscosity and density of these mixtures were evaluated at 298.15K.

Applicazioni

2-Butanone (Methyl ethyl ketone) may be employed as solvent for the methylation agent [11C]methyl trifluoromethanesulfonate ([11C]CH3OTf), during the completely automated radiosynthesis of 2-(4-N-[11C]methylaminophenyl)-6-hydroxybenzothiazole ([11C]PIB). It may be used in the synthesis of nanocontainer composed of 6 bowl-shaped cavitands. In the nanocontainer, cavitands were joined by 12 -CH=N-CH2CH2-N=CH- linkers.

Pittogrammi

FlameExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Organi bersaglio

Central nervous system

Rischi supp

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

30.2 °F - closed cup

Punto d’infiammabilità (°C)

-1 °C - closed cup


Certificati d'analisi (COA)

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A volumetric and viscosity study for the mixtures of 1-n-butyl-3-methylimidazolium tetrafluoroborate ionic liquid with acetonitrile, dichloromethane, 2-butanone and N, N-dimethylformamide.
Wang J, et al.
Green Chemistry, 5(5), 618-622 (2003)
C Philippe et al.
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A simple one-pot multicomponent synthesis of an octahedral nanocontainer molecule.
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Metabolites of the tobacco-specific nitrosamine, 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone, a potent pulmonary carcinogen, have been quantified in the urine of 11 smokers. They were not detected in nonsmokers' urine. The metabolites, 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanol and its glucuronide, were detected in quantities of 0.23-1.0 and 0.57-6.5
L B Goldsmith et al.
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Irritant contact dermatitis along with an increased transepidermal water loss can result from exposing the skin to solvents. A study of the interaction of various solvents with human stratum corneum was made using thin-layer chromatography. Comparison of 10 solvents (trichloroethylene

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