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237078

Sigma-Aldrich

Aluminum chloride hexahydrate

ReagentPlus®, 99%

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About This Item

Formula empirica (notazione di Hill):
AlCl3 · 6H2O
Numero CAS:
Peso molecolare:
241.43
Numero CE:
Numero MDL:
Codice UNSPSC:
12352302
ID PubChem:
NACRES:
NA.55
Saggio:
99%
Stato:
crystalline solid
crystals or chunks

Tensione di vapore

1 mmHg ( 100 °C)

Livello qualitativo

Nome Commerciale

ReagentPlus®

Saggio

99%

Stato

crystalline solid
crystals or chunks

Impiego in reazioni chimiche

reagent type: catalyst
core: aluminum

pH

2.5-3.5 (20 °C)

Stringa SMILE

Cl[Al](Cl)Cl.O.O.O.O.O.O

InChI

1S/Al.3ClH.6H2O/h;3*1H;6*1H2/q+3;;;;;;;;;/p-3
JGDITNMASUZKPW-UHFFFAOYSA-K

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Descrizione generale

Aluminum chloride hexahydrate is a nonflammable compound widely employed as a catalyst in organic synthesis. In addition to being extremely soluble in water, it is also soluble in alcohol, ether, glycerol, propylene glycol, and acetonitrile. It has many uses, including the refinement of crude oil, the production of deodorants and antiperspirant products, the dyeing of fabrics, textile finishing.

Applicazioni

Aluminum chloride hexahydrate is used as a catalyst:
  • In the synthesis of corresponding THP (tetrahydropyranylation) ether from alcohol or phenol, and 3,4-dihydro-2H-pyran (DHP).
  • In the direct esterification of levulinic acid and ethanol to produce ethyl levulinate.
  • In the synthesis of gem-dihydroperoxides from ketones and aldehydes.

Note legali

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pittogrammi

Health hazardCorrosion

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Eye Dam. 1 - Skin Corr. 1B - STOT RE 1

Organi bersaglio

Lungs

Rischi supp

Codice della classe di stoccaggio

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


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I clienti hanno visto anche

[Axillary hyperhydrosis. Local treatment with 25% aluminum chloride hexahydrate in absolute alcohol].
F Brandrup et al.
Ugeskrift for laeger, 140(35), 2106-2109 (1978-08-28)
Mark Baranov et al.
Inorganic chemistry, 58(13), 8877-8883 (2019-06-30)
While sophisticated computational methods can predict 31P NMR spectra of phosphorus atoms encapsulated within Keggin-derived heteropoly tungstate and molybdate cluster anions, calculated and experimental chemical shift values typically deviate considerably from one another. Motivated by the observation that experimentally determined
Aluminium (III) chloride hexahydrate: an efficient and versatile reagent in organic synthesis.
Sarma SD, et al.
ARKIVOC (Gainesville, FL, United States), 1, 243-263 (2013)
C L Goh
International journal of dermatology, 29(5), 368-370 (1990-06-01)
The efficacy of topical aluminium chloride hexahydrate 20% W/W ethanol (ACH) in the treatment symptomatic palmar hyperhidrosis was studied in 12 patients. A half-sided control single blind (assessor blind) study was done. Patients applied ACH on one palm daily for
A neutron and X-ray diffraction investigation of aluminum chloride hexahydrate.
Buchanan DR and Harris PM.
Acta Crystallographica Section B, Structural Science, 24(7), 954-960 (1968)

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