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T82805

Sigma-Aldrich

Triphenylethylene

99%

Sinonimo/i:

1,1,2-Triphenylethene, 1,1,2-Triphenylethylene, 1,1′,1′′-(1-Ethenyl-2-ylidene)tris[benzene], 1,2-Diphenylethenylbenzene, Benzilidenediphenylmethane, Ethene-1,1,2-triyltribenzene

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About This Item

Formula condensata:
C6H5CH=C(C6H5)2
Numero CAS:
58-72-0
Peso molecolare:
256.34
Beilstein:
1867462
Numero CE:
200-395-1
Numero MDL:
MFCD00004765
Codice UNSPSC:
12352100
ID PubChem:
24900519
NACRES:
NA.22

Saggio

99%

Punto di fusione

69-71 °C (lit.)

Stringa SMILE

c1ccc(cc1)\C=C(/c2ccccc2)c3ccccc3

InChI

1S/C20H16/c1-4-10-17(11-5-1)16-20(18-12-6-2-7-13-18)19-14-8-3-9-15-19/h1-16H
MKYQPGPNVYRMHI-UHFFFAOYSA-N

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Categorie correlate

Applicazioni

Triphenylethylene is an aromatic hydrocarbon, which can be used as a starting material to prepare 2,2,3-triphenyloxirane by asymmetric epoxidation reaction using fluorous chiral manganese complex as a catalyst. It is also used to prepare dihydro-4,5,5-triphenyl-2(3H)-furanone by reacting with acetic anhydride in the presence of MnO2 and NaOAc.

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

Certificati d'analisi (COA)

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Perylene ≥99%

Sigma-Aldrich

P11204

Perylene

2,6-di-tert-butil-4-metilfenolo Pharmaceutical Secondary Standard; Certified Reference Material

Supelco

PHR1117

2,6-di-tert-butil-4-metilfenolo

2,6-di-tert-butil-4-metilfenolo ≥99.0% (GC), powder

Sigma-Aldrich

B1378

2,6-di-tert-butil-4-metilfenolo

Trietilammina ≥99%

Sigma-Aldrich

T0886

Trietilammina

Yuliya Dobrydneva et al.
Journal of cardiovascular pharmacology, 50(4), 380-390 (2007-12-01)
The anti-estrogenic drug tamoxifen, which is used therapeutically for treatment and prevention of breast cancer, can lead to the development of thrombosis. We found that tamoxifen rapidly increased intracellular free calcium [Ca2+]i in human platelets from both male and female
H Wiseman et al.
Chemico-biological interactions, 79(2), 229-243 (1991-01-01)
The azole antifungal drug ketoconazole was found to inhibit Fe(III)-ascorbate dependent lipid peroxidation using either rat liver microsomes or ox-brain phospholipid liposomes as the substrate. It also inhibited microsomal peroxidation induced by the Fe(III)-ADP/NADPH system. The related azoles, miconazole and
Asymmetric epoxidation of alkenes in fluorinated media, catalyzed by second-generation fluorous chiral (Salen) manganese complexes
Cavazzini M, et al.
European Journal of Organic Chemistry, 2001(24), 4639-4649 (2001)
Chellakkan S Blesson et al.
Steroids, 71(11-12), 993-1000 (2006-09-13)
The study was aimed to investigate the interaction of D,L-ormeloxifene (Orm), a triphenylethylene and its hydroxy derivative with estrogen receptor subtypes alpha and beta, its influence on ERE-driven transcriptional activation and progesterone receptor expression. In competitive binding experiments using human
Speculation on the mechanism of action of triphenylethylene antioestrogens.
C D van den Koedijk et al.
Biochemical pharmacology, 47(11), 1927-1937 (1994-06-01)
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