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T81108

Sigma-Aldrich

1,3,5-Trioxane

≥99%

Sinonimo/i:

Metaformaldehyde, Trioxymethylene, sym.-Trioxane

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25 G
CHF 22.30
100 G
CHF 32.50
500 G
CHF 45.70
2 KG
CHF 138.00

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25 G
CHF 22.30
100 G
CHF 32.50
500 G
CHF 45.70
2 KG
CHF 138.00

About This Item

Formula empirica (notazione di Hill):
C3H6O3
Numero CAS:
Peso molecolare:
90.08
Beilstein:
102769
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

CHF 22.30


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Livello qualitativo

Saggio

≥99%

Temp. autoaccensione

777 °F

Limite di esplosione

29 %

Punto di fusione

59-62 °C (lit.)

Stringa SMILE

C1OCOCO1

InChI

1S/C3H6O3/c1-4-2-6-3-5-1/h1-3H2
BGJSXRVXTHVRSN-UHFFFAOYSA-N

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Applicazioni

1,3,5-Trioxane is widely used as a source of anhydrous formaldehyde.[1]
It can be used to synthesize:
  • Polyoxymethylene[2][3] and hyperbranched polyesters.[4]
  • Calixarenes such as calix[4]resorcinarene, calix[6]resorcinarene[5] and para-tert-butylcalix[8] and [9]arene.[6]
  • Various natural products including (−)-motuporin[7], (+)-sundiversifolide[8], (+)-lyconadin A and (−)-lyconadin B.[9]

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Flam. Sol. 1 - Repr. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

4.1B - Flammable solid hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

113.0 °F - closed cup

Punto d’infiammabilità (°C)

45 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Certificati d'analisi (COA)

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I clienti hanno visto anche

Slide 1 of 6

1 of 6

The Lyconadins: enantioselective total syntheses of (+)-lyconadin A and (−)-lyconadin B.
Beshore DC and Smith AB.
Journal of the American Chemical Society, 130(41), 13778-13789 (2008)
Single step synthesis of peripherally ?clickable? hyperbranched polyethers.
Saha A and Ramakrishnan S.
Macromolecules, 42(14), 4956-4959 (2009)
Hexahydro?1, 3, 5?tripropionyl?s?triazine.
Teeters WO and Gradsten MA.
Organic Syntheses, 51-51 (2003)
Cationic Copolymerization of 1, 3, 5-Trioxane with 1, 3-Dioxepane: A Comprehensive Approach to the Polyacetal Process.
Sharavanan K, et al.
Macromolecules, 42(22), 8702-8710 (2009)
Enantioselective synthesis of the protein phosphatase inhibitor (−)-motuporin.
Hu T and Panek JS.
Journal of the American Chemical Society, 124(38), 11368-11378 (2002)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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