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Merck
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Documenti fondamentali

B56501

Sigma-Aldrich

4-Bromoanisole

≥99.0%

Sinonimo/i:

1-Bromo-4-methoxybenzene

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50 G
CHF 37.10
100 G
CHF 41.70
500 G
CHF 175.00

CHF 37.10


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50 G
CHF 37.10
100 G
CHF 41.70
500 G
CHF 175.00

About This Item

Formula condensata:
BrC6H4OCH3
Numero CAS:
Peso molecolare:
187.03
Beilstein:
1237590
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

CHF 37.10


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Livello qualitativo

Saggio

≥99.0%

Stato

liquid

Indice di rifrazione

n20/D 1.564 (lit.)

P. ebollizione

223 °C (lit.)

Punto di fusione

9-10 °C (lit.)

Densità

1.494 g/mL at 25 °C (lit.)

Stringa SMILE

COc1ccc(Br)cc1

InChI

1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
QJPJQTDYNZXKQF-UHFFFAOYSA-N

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Descrizione generale

4-Bromoanisole is a useful brominating reagent.[1] It is formed as reaction product in the reaction between HOBr and anisole.[2] Suzuki coupling of 4-bromoanisole with phenylboronic acid catalyzed by palladium pincer complexes has been studied.[3] Heck Reaction of 4-bromoanisole with ethyl acrylates in room-temperature ionic liquids is reported to afford ethyl 4-methoxycinnamate.[4]

Applicazioni

4-Bromoanisole was used in the synthesis of aryl 1,3-diketones.[5]

Pittogrammi

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Avvertenze

Warning

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Skin Irrit. 2

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

201.2 °F

Punto d’infiammabilità (°C)

94 °C

Dispositivi di protezione individuale

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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Certificati d'analisi (COA)

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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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