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82320

Sigma-Aldrich

(±)-Propylene oxide

puriss. p.a., ≥99.5% (GC)

Sinonimo/i:

(±)-Methyloxirane, 1,2-Epoxypropane

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250 ML
CHF 45.10
1 L
CHF 115.00

CHF 45.10


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Cambia visualizzazione
250 ML
CHF 45.10
1 L
CHF 115.00

About This Item

Formula empirica (notazione di Hill):
C3H6O
Numero CAS:
Peso molecolare:
58.08
Beilstein:
79763
Numero CE:
Numero MDL:
Codice UNSPSC:
12162002
ID PubChem:
NACRES:
NA.23

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Densità del vapore

2 (vs air)

Tensione di vapore

29.43 psi ( 55 °C)
8.59 psi ( 20 °C)

Grado

puriss. p.a.

Saggio

≥99.5% (GC)

Stato

liquid

Temp. autoaccensione

1378 °F

Limite di esplosione

37 %

Impurezze

≤0.1% water

Residuo dopo evaporazione

≤0.005%

Indice di rifrazione

n20/D 1.366 (lit.)
n20/D 1.366

P. ebollizione

34 °C (lit.)

Punto di fusione

−112 °C (lit.)

Densità

0.83 g/mL at 25 °C (lit.)

Cationi in tracce

Al: ≤0.5 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg
Li: ≤0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤0.5 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

Condizioni di spedizione

wet ice

Temperatura di conservazione

2-8°C

Stringa SMILE

CC1CO1

InChI

1S/C3H6O/c1-3-2-4-3/h3H,2H2,1H3
GOOHAUXETOMSMM-UHFFFAOYSA-N

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Descrizione generale

(±)-Propylene oxide (PPO) belongs to the class of monomers known as epoxides or oxiranes. It is used as a raw material in the preparation n of polyurethane foam and polyether polyols, which are used in the production of polyurethane elastomers, polyurethane plastics, adhesives, sealants, and coatings. These materials find applications in industries such as automotive, construction, electronics, and textiles. PPO-based polymers possess flexibility and elasticity as inherent properties, making them well-suited for applications that demand materials with excellent resilience, stretchability, and impact resistance. Additionally, PPO-derived polymers are biocompatible, which makes them suitable for applications in various fields such as biomedical engineering, drug delivery, and tissue engineering.[1][2][3]

Applicazioni

Propylene oxide can be used as a starting material to synthesize:
  • Poly(3-hydroxybutyrate), a biodegradable and biocompatible polyester, by carbonylative polymerization.
  • Poly (propylene-ram-ε-caprolactone carbonate) (PPCL) and poly (propylene carbonate) (PPC), which are applicable as drug carriers.
Propylene oxide may be used in the production of polyether polyols, propylene glycols, propylene glycol ethers.

Applicazioni

N° Catalogo
Descrizione
Determinazione del prezzo

Avvertenze

Danger

Classi di pericolo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 1 - Muta. 1B - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

-36.4 °F - Equilibrium method

Punto d’infiammabilità (°C)

-38 °C - Equilibrium method

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles


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Josep Casamada Ribot et al.
Chemical communications (Cambridge, England), 46(37), 6971-6973 (2010-08-24)
The aqueous gelation of a quaternary ammonium oligo(propylene oxide)-based ionic liquid yields ion gels with a reverse thermoresponsive behavior (i.e., mechanical moduli and viscosity increase with temperature) and enhanced ionic conductivities.
Javix Thomas et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(16), 4582-4587 (2011-03-25)
Chirality recognition in the hydrogen-bonded glycidol···propylene oxide complex has been studied by using rotational spectroscopy and ab initio calculations. An extensive conformational search has been performed for this binary adduct at the MP2/6-311++G(d,p) level of theory and a total of
Sascha Brunke et al.
PLoS pathogens, 10(10), e1004478-e1004478 (2014-10-31)
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Aude Bouchet et al.
The Journal of organic chemistry, 76(10), 4178-4181 (2011-04-08)
ECD and NMR experiments show that the complexation of propylene oxide (PrO) within the cavity of an enantiopure water-soluble cryptophane 1 in NaOH solution is enantioselective and that the (R)-PrO@PP-1 diastereomer is more stable than the (S)-PrO@PP-1 diastereomer with a
Satoshi Toda et al.
Blood, 123(25), 3963-3971 (2014-03-25)
Definitive erythropoiesis takes place at erythroblastic islands, where erythroblasts proliferate and differentiate in association with central macrophages. At the final stage of erythropoiesis, pyrenocytes (nuclei surrounded by plasma membranes) are excluded from erythroblasts, expose phosphatidylserine (PtdSer), and are engulfed by

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