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746746

Sigma-Aldrich

Lithium hexafluorophosphate solution

greener alternative

in ethylene carbonate and diethyl carbonate, 1.0 M LiPF6 in EC/DEC=50/50 (v/v), battery grade

Sinonimo/i:

1.0 M LiPF6 EC/DEC=50/50 (v/v)

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About This Item

Formula condensata:
LiPF6
Numero MDL:
Codice UNSPSC:
26111700
ID PubChem:
NACRES:
NA.23

Grado

battery grade

Livello qualitativo

Forma fisica

solution

Caratteristiche più verdi

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Concentrazione

(1.0 M LiPF6 in EC/DEC)

Impurezze

<15 ppm H2O
<50 ppm HF

Colore

APHA: <50

P. eboll.

130 °C

Densità

1.26 g/mL at 25 °C (lit.)

Anioni in tracce

chloride (Cl-): ≤1 ppm
sulfate (SO42-): ≤2 ppm

Cationi in tracce

Ca: ≤1 ppm
Fe: ≤1 ppm
K: ≤1 ppm
Na: ≤1 ppm
Pb: ≤1 ppm

applicazioni

battery manufacturing

Categoria alternativa più verde

Stringa SMILE

F[P-](F)(F)(F)(F)F.[Li+]

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1
AXPLOJNSKRXQPA-UHFFFAOYSA-N

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Descrizione generale

Lithium hexafluorophosphate solution in ethylene carbonate and diethyl carbonate is a class of electrolytic solution that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Applicazioni

LiPF6 EC/DMC is widely used as an electrolyte that is thermally stable in solvents. It can be mainly used in the fabrication of lithium-ion batteries.
Liquid electrolyte solutions play a key role in lithium ion batteries (LIB) acting as carrier of lithium ions between the cathode and anode. High purity and battery grade electrolyte solutions are thus crucial for lithium ion battery performance. The most common LIB electrolytes are derived from solutions of lithium salt, such as LiPF6 in non-aqueous solvents, example alkyl carbonates or solvent blend. The choice of the electrolyte solution is dependent on both the operating conditions like temperature and the nature of the electrode material in the LIB. The performance of the electrolyte solutions can be further modified with appropriate additives.
The ready-to-use electrolyte solutions are available in different solvent blends and can support a wide variety of lithium ion battery applications. These solutions are high purity and battery grade thus making them also suitable as standards in LIB research. Customized formulations can be made by inter-mixing the electrolyte solutions or by mixing appropriate of additives.

Altre note

Handling instructions:
  • Do not use with glass equipment
  • All work should be done very quickly under dry air to prevent electrolytes from water uptake and solvent vaporization.

Note legali

Product of MU Ionic Solutions Corp

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT RE 2 Oral

Organi bersaglio

Bone,Teeth, Kidney

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

86.0 °F

Punto d’infiammabilità (°C)

30 °C


Certificati d'analisi (COA)

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Comparison of the thermal stability of lithiated graphite in LiBOB EC/DEC and in LiPF6 EC/DEC
Jiang J and Dahn JR
Electrochemical and Solid-State Letters, 6(9), A180-A180 (2003)
Reactivity of charged LiVPO4F with 1 M LiPF6 EC: DEC electrolyte at high temperature as studied by accelerating rate calorimetry
Zhou F, et al.
Electrochemical Communications, 11(3), 589-591 (2009)
Lucht, B. L.;
Energy Production and Storage, 333-333 (2010)
Visualization of electrode-electrolyte interfaces in LiPF6/EC/DEC electrolyte for lithium ion batteries via in situ TEM
Zeng Z, et al.
Nano Letters, 14(4), 1745-1750 (2014)
Scrosati, B.;
Energy & Environmental Science, 4(9), 3287-3287 (2011)

Articoli

Solid-state Li batteries: Review of solid electrolytes, ion conduction, structures, and electrochemical processes.

Li-ion batteries are currently the focus of numerous research efforts with applications designed to reduce carbon-based emissions and improve energy storage capabilities.

The critical technical challenges associated with the commercialization of electric vehicle batteries include cost, performance, abuse tolerance, and lifespan.

Lithium-ion batteries offer high energy density and cyclic performance for portable electronic devices.

Vedi tutto

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