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723142

Sigma-Aldrich

Tris[2-(dimethylamino)ethyl]amine

97%

Sinonimo/i:

Me6TREN

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About This Item

Formula empirica (notazione di Hill):
C12H30N4
Numero CAS:
33527-91-2
Peso molecolare:
230.39
Numero MDL:
MFCD00015607
Codice UNSPSC:
12162002
ID PubChem:
329763980
NACRES:
NA.23

Livello qualitativo

100

Saggio

97%

Stato

liquid

Indice di rifrazione

n20/D 1.455

Densità

0.862 g/mL at 25 °C

Stringa SMILE

CN(C)CCN(CCN(C)C)CCN(C)C

InChI

1S/C12H30N4/c1-13(2)7-10-16(11-8-14(3)4)12-9-15(5)6/h7-12H2,1-6H3
VMGSQCIDWAUGLQ-UHFFFAOYSA-N

Categorie correlate

Descrizione generale

Tris[2-(dimethylamino)ethyl]amine (Me6TREN) is an aliphatic tertiary amine that forms a quadridentate ligand. It is majorly used in atom transfer radical polymerization (ATRP). It is a hexamethyl derivative of (2-aminoethyl)amine, also known as trenMe. It can be prepared by a modification of Ristempart′s synthesis.

Applicazioni

Atom Transfer Radical Polymerization (ATRP) ligand for the creation of telechelic polymers.
Me6TREN forms a complex with copper compounds which can potentially be used as ligands in metalloenzyme redox reactions.

Pittogrammi

Corrosion
GHS05

Avvertenze

Danger

Indicazioni di pericolo

H314

Classi di pericolo

Eye Dam. 1 - Skin Corr. 1B

Codice della classe di stoccaggio

8A - Combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

219.9 °F - closed cup

Punto d’infiammabilità (°C)

104.4 °C - closed cup

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Certificati d'analisi (COA)

Lot/Batch Number
MKCT2984
MKCL7208
MKCC8502
MKBV7794V
MKBP8925V

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Optimization of atom transfer radical polymerization using Cu (I)/tris (2-(dimethylamino) ethyl) amine as a catalyst
Queffelec J, et al.
Macromolecules, 33(23), 8629-8639 (2000)
Diminishing catalyst concentration in atom transfer radical polymerization with reducing agents
Matyjaszewski K, et al.
Proceedings of the National Academy of Sciences of the USA, 103(42), 15309-15314 (2006)
Trigonal bipyramidal complexes of bivalent manganese, iron, and zinc with tris (2-dimethylaminoethyl) amine
Ciampolini Mt and Nardi N
Inorganic Chemistry, 5(7), 1150-1154 (1966)
Xiaoli Zhang et al.
Asian journal of pharmaceutical sciences, 15(5), 605-616 (2020-11-17)
Tumor cells show acidic conditions compared with normal cells, which further inspires scientist to build nanocarrier responsive to tumor microenvironment (TME) for enhancing tumor therapeutic efficacy. Here, we report a pH-sensitive and biocompatible polyprodrug based on dextran-doxorubicin (DOX) prodrug (DOXDT)
Xia Song et al.
Biomacromolecules, 17(12), 3957-3963 (2016-10-25)
Paclitaxel (PTX), a hydrophobic anticancer drug, is facing several clinical limitations such as low bioavailability and drug resistance. To solve the problems, a well-defined β-cyclodextrin-poly(N-isopropylacrylamide) star polymer was synthesized and used as a nanocarrier to improve the water solubility and
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Articoli

ATRP Ligands & Initiators: Clean Functional Polymers

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

Micro Review of RAFT Polymerization

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Protocolli

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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