514586
4-Methoxy-TEMPO
97%
Sinonimo/i:
4-Methoxy-2,2,6,6-tetramethyl-1-piperidinyloxy, free radical
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About This Item
Formula empirica (notazione di Hill):
C10H20NO2
Numero CAS:
Peso molecolare:
186.27
Numero MDL:
Codice UNSPSC:
12352000
ID PubChem:
NACRES:
NA.22
Prodotti consigliati
Saggio
97%
Punto di fusione
40.5-44 °C (lit.)
Temperatura di conservazione
2-8°C
Stringa SMILE
COC1CC(C)(C)N([O])C(C)(C)C1
InChI
1S/C10H20NO2/c1-9(2)6-8(13-5)7-10(3,4)11(9)12/h8H,6-7H2,1-5H3
SFXHWRCRQNGVLJ-UHFFFAOYSA-N
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Descrizione generale
4-Methoxy-TEMPO (4-methoxy-2,2,6,6-tetramethyl-1-piperidinyloxy) is an aminoxyl free radical commonly employed for the oxidation reaction of alcohols (primary/secondary).[1] It has been proposed as hindered amine light stabiliser (HALS) model compound. Its reaction with irradiated dilute aqueous suspensions of photocatalytic nanoparticulate titanium dioxide was investigated by electron spin resonance (ESR) and electrospray ionization mass-spectrometry (ESI-MS).[2]
Applicazioni
4-Methoxy-TEMPO may be employed as catalyst for the synthesis of 2-substituted benzoxazoles, via aerobic oxidation reaction.[1]
Codice della classe di stoccaggio
11 - Combustible Solids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Dispositivi di protezione individuale
dust mask type N95 (US), Eyeshields, Gloves
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Y C Liu et al.
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The kinetics of reduction of nitroxides including 4-hydroxy-TEMPO, 4-methoxy-TEMPO and 4-hexanoyloxy-TEMPO, which are of different lipophilicities, by vitamin C in cationic, non-ionic and anionic micelles, i.e. CTAB, Triton X-100 and SDS, respectively, have been studied by FSR spectroscopy by a
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Nucleosides, nucleotides & nucleic acids, 23(11), 1723-1738 (2004-12-16)
Our work outlines the use of oxoammonium salts in a formal 1,2 addition process to olefins giving nucleoside analogs as products. Specifically, oxoammonium salts can be added to a solution of olefin and silylated heterocycle to give Methoxy TEMPO substituted
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