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463353

Sigma-Aldrich

tert-Butyl methacrylate

98%, contains 200 ppm monomethyl ether hydroquinone as inhibitor

Sinonimo/i:

1,1-Dimethylethyl methacrylate, tert -Butyl α-methacrylate, tert -Butyl methacrylate, Acryester TB

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About This Item

Formula condensata:
H2C=C(CH3)CO2C(CH3)3
Numero CAS:
585-07-9
Peso molecolare:
142.20
Numero CE:
209-548-7
Numero MDL:
MFCD00048245
Codice UNSPSC:
12162002
ID PubChem:
24870053
NACRES:
NA.23

Saggio

98%

contiene

200 ppm monomethyl ether hydroquinone as inhibitor

Indice di rifrazione

n20/D 1.415 (lit.)

P. eboll.

132 °C (lit.)

Densità

0.875 g/mL at 25 °C (lit.)

Temperatura di conservazione

2-8°C

Stringa SMILE

CC(=C)C(=O)OC(C)(C)C

InChI

1S/C8H14O2/c1-6(2)7(9)10-8(3,4)5/h1H2,2-5H3
SJMYWORNLPSJQO-UHFFFAOYSA-N

Applicazioni

tert-Butyl methacrylate (tert-BMA) can be used in the formation of homo and block copolymers by atom transfer radical polymerization (ATRP) for potential usage in coatings, biomaterials and flocculants.

Pittogrammi

FlameExclamation mark
GHS02,GHS07

Avvertenze

Warning

Indicazioni di pericolo

H226,H315,H335

Classi di pericolo

Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

86.0 °F - closed cup

Punto d’infiammabilità (°C)

30 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificati d'analisi (COA)

Cerca il Certificati d'analisi (COA) digitando il numero di lotto/batch corrispondente. I numeri di lotto o di batch sono stampati sull'etichetta dei prodotti dopo la parola ‘Lotto’ o ‘Batch’.

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Sigma-Aldrich

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Termination Kinetics of tert-Butyl Methacrylate and of n-Butyl Methacrylate Free-Radical Bulk Homopolymerizations
Buback M and Junkers T
Macromolecular Chemistry and Physics, 207(18), 1640-1650 (2006)
Phase behavior of linear polystyrene-block-poly (2-vinylpyridine)-block-poly (tert-butyl methacrylate) triblock terpolymers
Ludwigs S, et al.
Polymer, 44(22), 6815-6823 (2003)
Homo and block copolymers of tert-butyl methacrylate by atom transfer radical polymerization
Krishnan R and Srinivasan KSV
European Polymer Journal, 40(10), 2269-2276 (2004)
Hironori Kumagai et al.
European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V, 136, 29-37 (2019-01-15)
We are investigating an imaging agent for early detection of colorectal cancer. The agent, named the nanobeacon, is coumarin 6-encapsulated polystyrene nanospheres whose surfaces are covered with poly(N-vinylacetamide) and peanut agglutinin that reduces non-specific interactions with the normal mucosa and
Binbin Xu et al.
Scientific reports, 6, 39504-39504 (2016-12-22)
A series of fluorine-containing amphiphilic ABC triblock copolymers comprising hydrophilic poly(ethylene glycol) (PEG) and poly(methacrylic acid) (PMAA), and hydrophobic poly(p-(2-(4-biphenyl)perfluorocyclobutoxy)phenyl methacrylate) (PBPFCBPMA) segments were synthesized by successive atom transfer radical polymerization (ATRP). First, PEG-Br macroinitiators bearing one terminal ATRP initiating
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