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Key Documents

359009

Sigma-Aldrich

Cerium(IV) sulfate

Sinonimo/i:

Ceric sulfate, Cerium disulfate

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About This Item

Formula condensata:
Ce(SO4)2
Numero CAS:
Peso molecolare:
332.24
Numero CE:
Numero MDL:
Codice UNSPSC:
12161600
ID PubChem:
NACRES:
NA.22

Forma fisica

powder

Livello qualitativo

Impiego in reazioni chimiche

core: cerium
reagent type: catalyst

Densità

3.01 g/mL at 25 °C (lit.)

Stringa SMILE

[Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O

InChI

1S/Ce.2H2O4S/c;2*1-5(2,3)4/h;2*(H2,1,2,3,4)/q+4;;/p-4
VZDYWEUILIUIDF-UHFFFAOYSA-J

Applicazioni

Cerium(IV) sulfate can be used to catalyze:
  • Selective oxidation of secondary alcohols to the corresponding ketones using sodium bromate as the oxidant.
  • Direct sulfonation of methane with sulfur trioxide to methanesulfonic acid in sulfuric acid.
  • Synthesis of 14-aryl- or 14-alkyl-14H-dibenzo[aj]xanthenes from the condensation of 2-naphthol and aldehydes under solvent-free and microwave conditions.

Reactant for:
  • Preparation of spherical-like nanoparticles CeO2 nanoparticles for NO reductions reactions

  • Oxidizing agent

Altre note

may contain excess sulfate

Pittogrammi

CorrosionEnvironment

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Codice della classe di stoccaggio

8B - Non-combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves


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