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278505

Sigma-Aldrich

Sulfuryl chloride solution

1.0 M in methylene chloride

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About This Item

Formula condensata:
SO2Cl2
Numero CAS:
7791-25-5
Peso molecolare:
134.97
Numero MDL:
MFCD00011451
Codice UNSPSC:
12352300
ID PubChem:
24856819
NACRES:
NA.23

Forma fisica

liquid

Concentrazione

1.0 M in methylene chloride

Densità

1.352 g/mL at 25 °C

Stringa SMILE

ClS(Cl)(=O)=O

InChI

1S/Cl2O2S/c1-5(2,3)4
YBBRCQOCSYXUOC-UHFFFAOYSA-N

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Categorie correlate

Applicazioni


  • Palladium-Catalyzed Synthesis of Ammonium Sulfinates from Aryl Halides and a Sulfur Dioxide Surrogate: A Gas-and Reductant-Free Process: This study elaborates on using sulfuryl chloride for oxidative chlorination leading to sulfonyl chloride formation, which is important for synthetic organic chemistry (Emmett et al., 2014).

  • Combining Organometallic Reagents, the Sulfur Dioxide Surrogate DABSO, and Amines: A One‐Pot Preparation of Sulfonamides, Amenable to Array Synthesis: This research discusses an innovative one-pot method for preparing sulfonamides using sulfuryl chloride, highlighting its utility in streamlining complex syntheses (Deeming et al., 2015).

  • Interfacial polymerization: from chemistry to functional materials: The article illustrates the use of sulfuryl chloride in interfacial polymerization, a key technique for developing advanced materials with tailored properties (Zhang et al., 2020).

Avvertenze

Danger

Indicazioni di pericolo

H314,H331,H336,H351

Classi di pericolo

Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1C - STOT SE 3

Organi bersaglio

Central nervous system

Rischi supp

EUH014

Codice della classe di stoccaggio

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificati d'analisi (COA)

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Bicarbonato di sodio ACS reagent, ≥99.7%

Sigma-Aldrich

S6014

Bicarbonato di sodio

Dietiletere contains 1 ppm BHT as inhibitor, anhydrous, ≥99.7%

Sigma-Aldrich

296082

Dietiletere

Polystyrene sulfonyl chloride: a highly orthogonal linker resin for the synthesis of nitrogen-containing heterocycles.
Matthias Mentel et al.
Angewandte Chemie (International ed. in English), 48(32), 5841-5844 (2009-07-08)
Zhiyong Wu et al.
Organic letters, 15(6), 1270-1273 (2013-03-07)
An efficient and concise one-pot protocol to synthesize sulfonylated quinoline N-oxides via copper-catalyzed C-H bond activation has been developed. Commercially available and less expensive aryl sulfonyl chlorides were used as the sulfonylation reagents. Various 2-aryl sulfonyl quinolines were obtained in
Christopher Blackburn
ACS combinatorial science, 14(3), 150-154 (2012-02-11)
Reductive aminations and further transformations of an azo dye and fluorous tagged aldehyde are described. The intensely colored 2,4-dialkoxybenzyl protected amines undergo Fmoc-based peptide coupling, Suzuki reactions, and sulfonamide formation with product isolation facilitated by visual monitoring of fluorous solid
Iron-catalyzed desulfinylative C-C cross-coupling reactions of sulfonyl chlorides with grignard reagents.
Chandra M Rao Volla et al.
Angewandte Chemie (International ed. in English), 47(7), 1305-1307 (2008-01-05)
Vlad Martin-Diaconescu et al.
Inorganic chemistry, 48(3), 1038-1044 (2009-01-10)
The electronic structure of organic sulfonyl compounds of the form RSO(2)G (G = -Cl, -OH, -CH(3)) is investigated to evaluate the effect of aryl R groups on photocleavage of the S-G bond. Sulfur K-edge X-ray absorption spectroscopy (XAS) provides a
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