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261262

Sigma-Aldrich

Scandium

powder, 99.9% trace rare earth metals basis

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About This Item

Formula empirica (notazione di Hill):
Sc
Numero CAS:
Peso molecolare:
44.96
Numero CE:
Numero MDL:
Codice UNSPSC:
12141613
ID PubChem:
NACRES:
NA.23

Saggio

99.9% trace rare earth metals basis

Forma fisica

powder

Resistività

50.5 μΩ-cm, 0°C

P. eboll.

2836 °C (lit.)

Punto di fusione

1540 °C (lit.)

Densità

2.99 g/mL at 25 °C (lit.)

Stringa SMILE

[Sc]

InChI

1S/Sc
SIXSYDAISGFNSX-UHFFFAOYSA-N

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Applicazioni

Employed in solid state synthesis of unusual clusters, Sc19Br28Z4, (Z=Mn, Fe, Ru or Os). These clusters are of interest for their structure and magnetic properties.

Accessorio

N° Catalogo
Descrizione
Determinazione del prezzo

Pittogrammi

Flame

Avvertenze

Danger

Indicazioni di pericolo

Consigli di prudenza

Classi di pericolo

Flam. Sol. 1

Codice della classe di stoccaggio

4.1B - Flammable solid hazardous materials

Classe di pericolosità dell'acqua (WGK)

nwg

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


Certificati d'analisi (COA)

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Vincent Tran et al.
Organic letters, 14(23), 6100-6103 (2012-11-23)
Treatment of ynol ether-tethered dialkyl acetals with catalytic quantities of scandium triflate in CH(3)CN gives rise to five-, six-, and seven-membered alkoxycycloalkene carboxylates in good to excellent yields. Tri- and tetrasubstituted carbocyclic and heterocyclic alkenes may be formed by this
Nadine V Hanhan et al.
Organic letters, 14(9), 2218-2221 (2012-04-18)
The scandium(III)-catalyzed enantioselective Hosomi-Sakurai allylation of isatins with various substituted allylic silanes is described. A catalyst loading as low as 0.05 mol % is utilized at room temperature to afford the 3-allyl-3-hydroxy-2-oxindoles in excellent yields and enantioselectivity up to 99%
Marek Pruszyński et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 70(6), 974-979 (2012-04-03)
The positron-emitting radionuclide (44)Sc with a half-life of 3.97 h and a β(+) branching of 94.3% is of potential interest for clinical PET. As so far it is available from a (44)Ti/(44)Sc generator in Mainz, where long-lived (44)Ti decays to
Jacob S Kanady et al.
Journal of the American Chemical Society, 135(3), 1073-1082 (2012-12-18)
The oxygen-evolving complex (OEC) of photosystem II contains a Mn(4)CaO(n) catalytic site, in which reactivity of bridging oxidos is fundamental to OEC function. We synthesized structurally relevant cuboidal Mn(3)MO(n) complexes (M = Mn, Ca, Sc; n = 3,4) to enable
Andrea Olmos et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(16), 4894-4901 (2012-03-15)
This study demonstrates the first zeolite-catalyzed synthesis of piperidine derivatives, including peptidomimetics and indoloquinolizidine alkaloids. The approach developed utilizes a highly effective one-pot reaction cascade, through imine formation and imino-Diels-Alder reactions, promoted by scandium-loaded zeolites as a heterogeneous catalyst. The

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