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Sigma-Aldrich

Triphenyl phosphate

≥99%

Sinonimo/i:

Triphenoxyphosphine oxide

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About This Item

Formula condensata:
(C6H5O)3PO
Numero CAS:
Peso molecolare:
326.28
Beilstein:
1888236
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

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Tensione di vapore

1.3 mmHg ( 200 °C)

Livello qualitativo

Saggio

≥99%

P. ebollizione

244 °C/10 mmHg (lit.)

Punto di fusione

48-50 °C (lit.)

Solubilità

acetone: soluble(lit.)
alcohol: moderately soluble(lit.)
benzene: soluble(lit.)
chloroform: soluble(lit.)
diethyl ether: soluble(lit.)
water: insoluble(lit.)

Gruppo funzionale

phosphate

Stringa SMILE

O=P(Oc1ccccc1)(Oc2ccccc2)Oc3ccccc3

InChI

1S/C18H15O4P/c19-23(20-16-10-4-1-5-11-16,21-17-12-6-2-7-13-17)22-18-14-8-3-9-15-18/h1-15H
XZZNDPSIHUTMOC-UHFFFAOYSA-N

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Descrizione generale

Triphenyl phosphate, an organophosphorus flame retardant (PFR), was determined in human milk sample[1].

Applicazioni

Triphenyl phosphate was used as an internal standard in the screening and quantification of pesticide residues in vegetables and fruits[2].

Pittogrammi

Environment

Avvertenze

Warning

Indicazioni di pericolo

Consigli di prudenza

Classi di pericolo

Aquatic Acute 1 - Aquatic Chronic 1

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

428.0 °F - closed cup

Punto d’infiammabilità (°C)

220 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Gloves


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Joon-Woo Kim et al.
Chemosphere, 116, 91-97 (2014-03-19)
In this study, the concentrations of 10 organophosphorus flame retardants (PFRs) were determined in 89 human breast milk samples collected from Japan, the Philippines and Vietnam. Among the targeted PFRs, tris(2-chloroexyl) phosphate (TCEP) and triphenyl phosphate (TPHP) were the predominant
Amer El-Batta et al.
The Journal of organic chemistry, 72(14), 5244-5259 (2007-06-15)
Water is demonstrated to be an effective medium for the Wittig reaction over a wide range of stabilized ylides and aldehydes. Despite sometimes poor solubility of the reactants, good chemical yields normally ranging from 80 to 98% and high E-selectivities
Chunsheng Liu et al.
Aquatic toxicology (Amsterdam, Netherlands), 128-129, 147-157 (2013-01-12)
Tris(1,3-dichloro-2-propyl) phosphate (TDCPP) and triphenyl phosphate (TPP) are frequently detected in biota, including fish. However, knowledge of the toxicological and molecular effects of these currently used flame retardants is limited. In the present study, an in vivo screening approach was
Rainer Hoenicke et al.
Environmental research, 105(1), 132-144 (2007-03-06)
While over seven million organic and inorganic compounds that have been indexed by the American Chemical Society's Chemical Abstracts Service in their CAS Registry are commercially available, most pollution monitoring programs focus only on those chemical stressors for which regulatory
Felix D Guerrero et al.
Journal of medical entomology, 43(5), 896-901 (2006-10-05)
The horn fly, Haematobia irritans irritans (L.) (Diptera: Muscidae), has become a problem for Brazilian cattle producers even though its introduction into Brazil is relatively recent. Failure to control this cattle pest is becoming a concern, and horn fly populations

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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