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227269

Sigma-Aldrich

Benzyl isocyanate

99%

Sinonimo/i:

α-Isocyanatotoluene, (Isocyanatomethyl)benzene, 1-(Isocyanatomethyl)benzene, Phenylmethyl isocyanate

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About This Item

Formula condensata:
C6H5CH2NCO
Numero CAS:
3173-56-6
Peso molecolare:
133.15
Beilstein:
636508
Numero CE:
221-640-9
Numero MDL:
MFCD00009701
Codice UNSPSC:
12352100
ID PubChem:
24853269
NACRES:
NA.22

Livello qualitativo

100

Saggio

99%

Forma fisica

liquid

Indice di rifrazione

n20/D 1.526 (lit.)

P. eboll.

101-104 °C/33 mmHg (lit.)

Densità

1.078 g/mL at 25 °C (lit.)

Stringa SMILE

O=C=NCc1ccccc1

InChI

1S/C8H7NO/c10-7-9-6-8-4-2-1-3-5-8/h1-5H,6H2
YDNLNVZZTACNJX-UHFFFAOYSA-N

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Descrizione generale

Benzyl isocyanate inhibits the formation of benzo[a]pyrene (BP)-DNA adduct and posses chemopreventive properties.

Applicazioni

Benzyl isocyanate was used to investigate the kinetics of isocyanate derivatization reaction in a continuous flow glass microfluidics chip. It was also used in a multicomponent, stereospecific synthesis of 1,3-oxazinane-2,4-diones employing an Al-salph complex (674699).

Pittogrammi

Flame
GHS02

Avvertenze

Warning

Indicazioni di pericolo

H226

Classi di pericolo

Flam. Liq. 3

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

113.0 °F - closed cup

Punto d’infiammabilità (°C)

45 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificati d'analisi (COA)

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Sigma-Aldrich

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Monica Brivio et al.
Analytical chemistry, 77(21), 6852-6856 (2005-11-01)
The reaction of propyl isocyanate (2), benzyl isocyanate (3), and toluene-2,4-diisocyanate (4) with 4-nitro-7-piperazino-2,1,3-benzoxadiazole (1) to yield the corresponding urea derivatives 5 was carried out in a continuous flow glass microfluidics chip. Real-time monitoring of the derivatization reactions was done
W A Smith et al.
Mutation research, 425(1), 143-152 (1999-03-20)
The large (>2000) and expanding number of natural and synthetic agents with potential cancer chemopreventive properties renders it economically and physically impossible to test each of these agents for their efficacy in the widely accepted 2-year animal bioassay and clinical
Tamara L Church et al.
Journal of the American Chemical Society, 129(26), 8156-8162 (2007-06-15)
The use of mechanistic information to develop a new, catalytic multicomponent reaction is described. The complex [(salph)Al(THF)2]+[Co(CO)4]- (1, salph = N,N'-o-phenylenebis(3,5-di-tert-butylsalicylideneimine), THF = tetrahydrofuran), which is known to carbonylate epoxides, aziridines, and beta-lactones, was used to catalyze the synthesis of
Eliana Esparza et al.
Phytochemistry, 179, 112502-112502 (2020-09-02)
Postharvest processing of maca (Lepidium meyenii Walp., Brassicaceae), a traditional high-altitude Andean root crop, involves slow field drying prior to milling into flour. The progressive tissue dehydration and release of hydrolytic enzymes and substrates from cellular compartments results in the
Liang Li et al.
Analytical and bioanalytical chemistry, 411(21), 5465-5479 (2019-06-10)
A benzylureido-β-cyclodextrin was synthesized by the reaction of 6-amino-β-cyclodextrin with an active benzyl isocyanate. Then, it was bonded to silica gel by a thiol-ene addition reaction, obtaining a new benzylureido-β-cyclodextrin-based chiral stationary phase (BzCDP). Its chemical structure was characterized by
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