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Documenti fondamentali

211176

Sigma-Aldrich

Selenous acid

98%

Sinonimo/i:

Selenious acid

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10 G
CHF 47.20
50 G
CHF 72.10
250 G
CHF 247.00

CHF 47.20


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Cambia visualizzazione
10 G
CHF 47.20
50 G
CHF 72.10
250 G
CHF 247.00

About This Item

Formula condensata:
H2SeO3
Numero CAS:
Peso molecolare:
128.97
Numero CE:
Numero MDL:
Codice UNSPSC:
12352301
ID PubChem:
NACRES:
NA.22

CHF 47.20


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Saggio

98%

Stato

solid

Punto di fusione

70  °C ((lit.))
70 °C (dec.) (lit.)

Solubilità

water: 50 mg/mL

Densità

3.004  g/mL at 25 °C ((lit.))
3.004 g/mL at 25 °C (lit.)

Stringa SMILE

O[Se](O)=O
O[Se](O)=O

InChI

1S/H2O3Se/c1-4(2)3/h(H2,1,2,3)
1S/H2O3Se/c1-4(2)3/h(H2,1,2,3)
MCAHWIHFGHIESP-UHFFFAOYSA-N
MCAHWIHFGHIESP-UHFFFAOYSA-N

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Categorie correlate

Applicazioni

Selenous acid can be used as a reagent to synthesize:
  • α-Ketoacectals by reacting with acetophenones and triethylorthoformate in the presence of boron trifluoride etherate as a catalyst[1].
  • 4-Formyl-7-methylcoumarin using 4,7-dimethylcoumarin in the presence of xylene as a solvent[2].
  • Selenium substituted quinoxaline derivatives from 2,3-dichloro quionoxaline.

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Codice della classe di stoccaggio

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Certificati d'analisi (COA)

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One-pot synthesis of alpha-ketoacetals from aryl methyl ketones in the presence of selenous acid catalyzed by boron trifluoride etherate
Kharkongor I, et al.
Tetrahedron Letters, 56, 4359-4362 (2015)
The synthesis of novel coumarin dyes and the study of their photoreaction properties
Wang T, et al.
Dyes and Pigments, 75, 104-110 (2007)
D Seidel et al.
Journal of clinical chemistry and clinical biochemistry. Zeitschrift fur klinische Chemie und klinische Biochemie, 16(7), 407-411 (1978-07-01)
A simple one-vial-method was developed for the quantitative determination of sphingomyelinase activity in human leukocytes and urine, using [14C-methyl] sphingomyelin. The measured activities of healthy control persons show a higher scatter in (n=50) urine (1.2 +/- 0.5 nmol/h . ml
Thomas G Back et al.
Journal of the American Chemical Society, 124(41), 12104-12105 (2002-10-10)
1,2-Oxaselenolane Se-oxide is a novel cyclic seleninate ester that functions as a remarkably efficient glutathione peroxidase mimetic by catalyzing the reduction of tert-butyl hydroperoxide to tert-butyl alcohol in the presence of benzyl thiol. The seleninate ester can be conveniently generated
Y Kayanoki et al.
Journal of biochemistry, 119(4), 817-822 (1996-04-01)
Selenium-dependent glutathione peroxidase (GPx) plays a protective role in oxidative stress-induced apoptosis. In this study, we demonstrated that MDBK cells, a bovine renal epithelial cell line, exhibited internucleosomal DNA fragmentation characteristic of apoptotic cell death under selenium-deficient conditions with lower

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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