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Sigma-Aldrich

N,O-bis(trimetilsilil)trifluoroacetamide

≥99%

Sinonimo/i:

BSTFA

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5 G
CHF 33.00
25 G
CHF 91.70
100 G
CHF 327.00

CHF 33.00


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5 G
CHF 33.00
25 G
CHF 91.70
100 G
CHF 327.00

About This Item

Formula condensata:
CF3C[=NSi(CH3)3]OSi(CH3)3
Numero CAS:
Peso molecolare:
257.40
Beilstein:
2050024
Numero CE:
Numero MDL:
Codice UNSPSC:
12352111
ID PubChem:
NACRES:
NA.22

CHF 33.00


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Grado

synthesis grade

Livello qualitativo

Saggio

≥99%

Stato

liquid

Indice di rifrazione

n20/D 1.384 (lit.)

P. ebollizione

45-50 °C/14 mmHg (lit.)

Densità

0.969 g/mL at 25 °C (lit.)

Gruppo funzionale

fluoro

Stringa SMILE

C[Si](C)(C)O\C(=N\[Si](C)(C)C)C(F)(F)F

InChI

1S/C8H18F3NOSi2/c1-14(2,3)12-7(8(9,10)11)13-15(4,5)6/h1-6H3/b12-7+
XCOBLONWWXQEBS-KPKJPENVSA-N

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Descrizione generale

N,O-Bis(trimethylsilyl)trifluoroacetamide is an organosilicon reagent for trimethylsilylation, deprotection, dehydrogenation, allylic alkylation, nitronate formation, and Claisen rearrangement.

BSTFA is a silylating agent used in the synthesis of 4-Quinolones.[1]

Applicazioni

N,O-Bis(trimethylsilyl)trifluoroacetamide can be used as a derivatization reagent for the determination of the estrogens estrone and 17α-ethinylestradiol by gas chromatography-mass spectrometry.

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Pittogrammi

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Avvertenze

Warning

Indicazioni di pericolo

Classi di pericolo

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

93.2 °F

Punto d’infiammabilità (°C)

34 °C

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Synthesis of 4-Quinolones: N, O-Bis (trimethylsilyl) acetamide-Mediated Cyclization with Cleavage of Aromatic C--O Bond
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European Journal of Organic Chemistry, 2016, 2336-2350 (2016)
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Electro membrane extraction-solid-liquid phase microextraction (EME-SLPME) was developed for the first time to determine phenolic contaminants in water. The extraction system consisted of a solid/liquid interface that permitted a three-phase microextraction approach involving an aqueous sample (donor phase): an organic

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

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