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221716

Sigma-Aldrich

Ammonium oxalate monohydrate

ACS reagent, ≥99%

Synonyme(s) :

Oxalic acid diammonium salt

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100 G
40.10 CHF
500 G
95.50 CHF
2.5 KG
745.00 CHF

About This Item

Formule linéaire :
(NH4)2C2O4 · H2O
Numéro CAS:
Poids moléculaire :
142.11
Beilstein:
3759830
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352300
ID de substance PubChem :
Nomenclature NACRES :
NB.24

40.10 CHF


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Devis pour commande en gros

Qualité

ACS reagent

Pression de vapeur

<0.1 hPa ( 20 °C)

Essai

≥99%
99.0-101.0% (ACS specification)

Forme

crystalline powder
crystals or granules

Impuretés

≤0.005% insolubles

Résidus de calcination

≤0.02%

pH

6-7 (25 °C, 14.2 g/L)

Pf

133 °C (dec.) (lit.)

Traces d'anions

chloride (Cl-): ≤0.002%
sulfate (SO42-): ≤0.002%

Traces de cations

Fe: ≤2 ppm
heavy metals: ≤5 ppm (by ICP)

Chaîne SMILES 

OC(C(O)=O)=O.N.O.N

InChI

1S/C2H2O4.2H3N.H2O/c3-1(4)2(5)6;;;/h(H,3,4)(H,5,6);2*1H3;1H2

Clé InChI

MSMNVXKYCPHLLN-UHFFFAOYSA-N

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Catégories apparentées

Description générale

Ammonium oxalate monohydrate is a diammonium salt of oxalic acid. Its refined crystal structure has been investigated by three-dimensional diffraction studies.[1] Influence of bivalent [Mn(II), Co(II), Ni(II)] and trivalent cations [Fe(III), Cr(III)] impurities on the growth rates of ammonium oxalate monohydrate crystals has been described.[2] Its space group and unit cell parameters have been analyzed by neutron diffraction studies.[3] Its IR spectra have been compared with that of isolated coal-solubilizing agent (CSA).[4]

Application

Ammonium oxalate monohydrate may be used in the preparation of tetramethylammonium oxalate.[5]

Produit(s) apparenté(s)

Réf. du produit
Description
Tarif

Pictogrammes

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Mention d'avertissement

Warning

Mentions de danger

Classification des risques

Acute Tox. 4 Oral - Eye Irrit. 2

Code de la classe de stockage

13 - Non Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Consulter la Bibliothèque de documents

A convenient method for preparation of quaternary ammonium salts.
Markowitz M.
The Journal of Organic Chemistry, 22(8), 983-984 (1957)
Yeonho Kim et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(46), 10510-10518 (2020-03-27)
In this work, environmentally friendly photocatalysts with attractive catalytic properties are reported that have been prepared by introducing SnO2 quantum dots (QDs) directly onto ZnSe(N2 H4 )0.5 substrates to induce advantageous charge separation. The SnO2 /ZnSe(N2 H4 )0.5 nanocomposites could
Sina Matavos-Aramyan et al.
Free radical biology & medicine, 106, 158-167 (2017-02-19)
Three novel modified advanced oxidation process systems including ascorbic acid-, pro-oxidants- and ascorbic acid-pro-oxidants-modified Fenton system were utilized to study the disinfection efficiency on Cryptosporidium-contaminated drinking water samples. Different concentrations of divalent and trivalent iron ions, hydrogen peroxide, ascorbic acid
Neutron diffraction study of ammonium oxalate monohydrate,(NH4)2C2O4.H2O.
Padmanabhan VM, et al.
Acta Crystallographica, 18(3), 567-568 (1965)
Effect of impurities on metastable zone width for the growth of ammonium oxalate monohydrate crystals from aqueous solutions.
Sangwal K and Mielniczek-Brzoska E.
Journal of Crystal Growth, 267(3), 662-675 (2004)

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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