Thionyl-chloride (TCl) is used in the manufacture of lithium batteries, producing SO2 and HCl fumes on contact with water. We report two cases of accidental TCl exposure resulting in lung injury that may vary from a relatively mild and reversible
Langmuir : the ACS journal of surfaces and colloids, 20(12), 4989-4995 (2005-06-30)
This paper describes a novel approach for the surface modification of a cation-exchange membrane, bearing sulfonate groups, by a cationic layer. The modification procedure involved the chlorosulfonation of the sulfonate groups of the base membrane with thionyl chloride, followed by
Dalton transactions (Cambridge, England : 2003), 40(24), 6547-6554 (2011-05-18)
One-pot syntheses of three new enantiopure heteroscorpionate ligands derived from (+)-camphor or (-)-menthone are described. The ligands are obtained by reacting pyrazoles derived from (+)-camphor or (-)-menthone with sodium hydride and thionyl chloride. Subsequent reactions with pyridine and various aldehydes
Physical chemistry chemical physics : PCCP, 7(2), 301-309 (2005-01-21)
New theoretical and experimental results for the ultraviolet photodissociation dynamics of thionyl chloride (SOCl2) are presented and combined with existing data from a variety of sources in order to provide a unified view of the photodissociation dynamics of SOC12. Time-dependent
The Journal of organic chemistry, 73(1), 312-315 (2007-12-07)
A simple, one-pot preparation of cyclic amines via efficient chlorination of amino alcohols with use of SOCl(2) has been developed. This approach obviates the need for the classical N-protection/O-activation/cyclization/deprotection sequence commonly employed for this type of transformation. The reaction pathways
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