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205680

Sigma-Aldrich

Palladium sur charbon

greener alternative

extent of labeling: 5 wt. % loading (dry basis), matrix activated carbon support

Synonyme(s) :

Pd/C

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10 G
167.00 CHF
50 G
621.00 CHF
100 G
1 160.00 CHF

167.00 CHF

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Sélectionner une taille de conditionnement

Changer de vue
10 G
167.00 CHF
50 G
621.00 CHF
100 G
1 160.00 CHF

About This Item

Formule linéaire :
Pd
Poids moléculaire :
106.42
Numéro MDL:
MFCD03457879
Code UNSPSC :
12141733
eCl@ss :
38191001
ID de substance PubChem :
24852218
Nomenclature NACRES :
NA.22

167.00 CHF

Check Cart for Availability
Devis pour commande en gros

Forme

powder

Niveau de qualité

200

Pertinence de la réaction

core: palladium
reagent type: catalyst

Capacité de réaction

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

Caractéristiques du produit alternatif plus écologique

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Ampleur du marquage

5 wt. % loading (dry basis)

Matrice

activated carbon support

Autre catégorie plus écologique

Enabling,

Chaîne SMILES 

[Pd]

InChI

1S/Pd

Clé InChI

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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Catégories apparentées

Description générale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Réactions catalysées :
  • Réaction de Stille
  • Réactions d'hydrogénation
  • Couplage croisé de Suzuki-Miyaura et réactions de Heck-Mizoroki
  • Désoxygénation
  • Réactions d'oxydation
  • Réactions de couplage
Palladium on carbon (Pd/C) (5 wt. % loading (dry basis), matrix activated carbon support) can be used for a variety of applications, such as:

  • a catalyst for hydrodechlorination of dichlorodifluoromethane (CCl2F2), which is a known greenhouse gas[1]
  • a catalyst for Heck reactions of aryl halides in ionic liquids[2]
  • an anode catalyst for the fabrication of direct formic acid fuel cells (DFAFC)[3]
  • a cost-effective electrocatalyst for the oxidation of methanol[4]
  • in the catalytic hydrogenation of chemical hydrides for the production of hydrogen[5]
  • a catalyst in Suzuki-Mayaura reaction[6]
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Gloves, type N95 (US)

Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number
MKCR5541
MKCQ8119
MKCQ9898
MKCR2834
MKCQ4023

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Soosan Kim et al.
Journal of hazardous materials, 392, 122464-122464 (2020-03-21)
The accumulation of industrial plastic waste in the environment is a global growing concern. Thermochemical process is a preferred method to dispose plastic waste mainly because it can reduce volume of the waste; however, the thermochemical disposal of plastic waste
Svilen P Simeonov et al.
ChemSusChem, 12(12), 2748-2754 (2019-05-06)
A new scalable synthesis of pentane-1,2,5-triol from the furanics platform has been developed. Excellent yields of up to 92 % are obtained under flow conditions by using readily available catalysts from the existing pool. The strategy exploits the highly functionalized Achmatowicz
Characterisation of the deactivation of platinum and palladium supported on activated carbon used as hydrodechlorination catalysts
Ordonez S, et al.
Applied Catalysis. B, Environmental, 31(2), 113-122 (2001)
Heterogeneous Heck reaction catalyzed by Pd/C in ionic liquid
Hagiwara H, et al.
Tetrahedron Letters, 42(26), 4349-4351 (2001)
Pd/C: an old catalyst for new applications-its use for the Suzuki-Miyaura reaction
Felpin F, et al.
European Journal of Organic Chemistry, 2006(12), 2679-2690 (2006)
Afficher tous les articles scientifiques apparentés

Questions

1–3 of 3 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. What is the particle size of this catalyst ? (205680 Pd/C 5%)

    1 answer

    1. The particle size is 325 mesh. Please see the link below for the particle size conversion table.
      https://www.sigmaaldrich.com/support/calculators-and-apps/particle-size-conversion-table

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