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143677

Sigma-Aldrich

2-(Bromomethyl)naphthalene

96%

Synonyme(s) :

β-(Bromomethyl)naphthalene, β-Naphthylmethyl bromide, (Naphthalen-2-yl)methyl bromide, 2-(Bromomethyl)naphthalene, 2-Menaphthyl bromide, 2-Naphthylmethyl bromide

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About This Item

Formule linéaire :
C10H7CH2Br
Numéro CAS:
939-26-4
Poids moléculaire :
221.09
Beilstein:
636546
Numéro CE :
213-359-5
Numéro MDL:
MFCD00004123
Code UNSPSC :
12352100
ID de substance PubChem :
24848601
Nomenclature NACRES :
NA.22
Le tarif et la disponibilité ne sont pas disponibles actuellement.

Niveau de qualité

100

Essai

96%

pb

213 °C/100 mmHg (lit.)

Pf

51-54 °C (lit.)

Groupe fonctionnel

bromo

Température de stockage

2-8°C

Chaîne SMILES 

BrCc1ccc2ccccc2c1

InChI

1S/C11H9Br/c12-8-9-5-6-10-3-1-2-4-11(10)7-9/h1-7H,8H2

Clé InChI

RUHJZSZTSCSTCC-UHFFFAOYSA-N

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Catégories apparentées

Application

2-(Bromomethyl)naphthalene (2-BMN) can be employed as a starting material in the synthesis of 2-(fluoromethyl)naphthalene [1], 2-naphthylmethyl azide [2], 2-naphthalenecarboxaldehyde [3], diselenide, bis(2-naphthalenylmethyl) [4], 1H-1,2,3-triazole, 4,4′-(1,4-phenylene)bis[1-(2-naphthalenylmethyl).[5]

Pictogrammes

CorrosionExclamation mark
GHS05,GHS07

Mention d'avertissement

Danger

Mentions de danger

H314,H317

Classification des risques

Skin Corr. 1B - Skin Sens. 1

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

230.0 °F - closed cup

Point d'éclair (°C)

110 °C - closed cup

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificats d'analyse (COA)

Lot/Batch Number
STBJ7258
STBJ6043
STBH2765
STBG0636V
STBC9168V

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

A novel and efficient method for the synthesis of dibenzyl diselenides
Tian F and Lu S
J. Chem. Res. (M), 2004(9), 632-633 (2004)
Dimeric and trimeric triazole based molecules as a new class of Hsp90 molecular chaperone inhibitors
Terracciano S, et al.
European Journal of Medicinal Chemistry, 65(9), 464-476 (2013)
Silica-based magnetic manganese nanocatalyst-applications in the oxidation of organic halides and alcohols
Sharma RK, et al.
ACS sustainable chemistry & engineering, 4(3), 1123-1130 (2016)
Probing the reactivity of o-phthalaldehydic acid/methyl ester: synthesis of N-isoindolinones and 3-arylaminophthalides
Mamidyala SK and Cooper MA
Chemical Communications (Cambridge, England), 49(75), 8407-8409 (2013)
Kuppuswamy Arumugam et al.
Inorganic chemistry, 46(8), 3283-3288 (2007-03-16)
The reaction of P4S10 with acyloins, RC(O)CH(OH)R, in refluxing dioxane, followed by the addition of alkylating agents, forms dithiolene thiophosphoryl thiolate compounds, (R2C2S2)P(S)(SR'), which are readily isolated and purified. The compounds that have been prepared and identified spectroscopically are those
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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